Open Access
Frontiers in Chemistry, volume 10
Novel family of nitrogen-rich energetic (1,2,4-triazolyl) furoxan salts with balanced performance
Publication type: Journal Article
Publication date: 2022-09-12
Journal:
Frontiers in Chemistry
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 5.5
ISSN: 22962646
PubMed ID:
36172000
General Chemistry
Abstract
Nitrogen-rich energetic materials comprised of a combination of several heterocyclic subunits retain their leading position in the field of materials science. In this regard, a preparation of novel high-energy materials with balanced set of physicochemical properties is highly desired. Herein, we report the synthesis of a new series of energetic salts incorporating a (1,2,4-triazolyl) furoxan core and complete evaluation of their energetic properties. All target energetic materials were well characterized with IR and multinuclear NMR spectroscopy and elemental analysis, while compound 6 was further characterized by single-crystal X-ray diffraction study. Prepared nitrogen-rich salts have high thermal stability (up to 232°C), good experimental densities (up to 1.80 g cm−3) and high positive enthalpies of formation (344–1,095 kJ mol−1). As a result, synthesized energetic salts have good detonation performance (D = 7.0–8.4 km s−1; p = 22–32 GPa), while their sensitivities to impact and friction are quite low.
Citations by journals
|
1
|
|
|
International Journal of Molecular Sciences
|
International Journal of Molecular Sciences
1 publication, 14.29%
|
|
ChemPlusChem
|
ChemPlusChem
1 publication, 14.29%
|
|
Chemistry - A European Journal
|
Chemistry - A European Journal
1 publication, 14.29%
|
|
Physical Chemistry Chemical Physics
|
Physical Chemistry Chemical Physics
1 publication, 14.29%
|
|
Russian Chemical Reviews
|
Russian Chemical Reviews
1 publication, 14.29%
|
|
Journal of Heterocyclic Chemistry
|
Journal of Heterocyclic Chemistry
1 publication, 14.29%
|
|
Journal of Chemical & Engineering Data
|
Journal of Chemical & Engineering Data
1 publication, 14.29%
|
|
1
|
Citations by publishers
|
1
2
3
|
|
|
Wiley
|
Wiley
3 publications, 42.86%
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 14.29%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
1 publication, 14.29%
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 14.29%
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
1 publication, 14.29%
|
|
1
2
3
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[0,0,0],"codes":[0,0,0],"imageUrls":["","",""],"datasets":[{"label":"Citations number","data":[1,3,3],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":["14.29","42.86","42.86"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["International Journal of Molecular Sciences","ChemPlusChem","Chemistry - A European Journal","Physical Chemistry Chemical Physics","Russian Chemical Reviews","Journal of Heterocyclic Chemistry","Journal of Chemical & Engineering Data"],"ids":[14627,21067,24708,1773,23802,3189,14227],"codes":[0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp"],"datasets":[{"label":"","data":[1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[14.29,14.29,14.29,14.29,14.29,14.29,14.29],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Wiley","Multidisciplinary Digital Publishing Institute (MDPI)","Royal Society of Chemistry (RSC)","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii","American Chemical Society (ACS)"],"ids":[11,202,123,9422,40],"codes":[0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp"],"datasets":[{"label":"","data":[3,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[42.86,14.29,14.29,14.29,14.29],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Larin A. A. et al. Novel family of nitrogen-rich energetic (1,2,4-triazolyl) furoxan salts with balanced performance // Frontiers in Chemistry. 2022. Vol. 10.
GOST all authors (up to 50)
Copy
Larin A. A., Pivkina A. N., Ananyev I. V., Khakimov D. V., Fershtat L. L. Novel family of nitrogen-rich energetic (1,2,4-triazolyl) furoxan salts with balanced performance // Frontiers in Chemistry. 2022. Vol. 10.
Cite this
RIS
Copy
TY - JOUR
DO - 10.3389/fchem.2022.1012605
UR - https://doi.org/10.3389%2Ffchem.2022.1012605
TI - Novel family of nitrogen-rich energetic (1,2,4-triazolyl) furoxan salts with balanced performance
T2 - Frontiers in Chemistry
AU - Larin, Alexander A
AU - Pivkina, Alla N
AU - Ananyev, Ivan V.
AU - Khakimov, Dmitry V.
AU - Fershtat, Leonid L
PY - 2022
DA - 2022/09/12 00:00:00
PB - Frontiers Media S.A.
VL - 10
PMID - 36172000
SN - 2296-2646
ER -
Cite this
BibTex
Copy
@article{2022_Larin,
author = {Alexander A Larin and Alla N Pivkina and Ivan V. Ananyev and Dmitry V. Khakimov and Leonid L Fershtat},
title = {Novel family of nitrogen-rich energetic (1,2,4-triazolyl) furoxan salts with balanced performance},
journal = {Frontiers in Chemistry},
year = {2022},
volume = {10},
publisher = {Frontiers Media S.A.},
month = {sep},
url = {https://doi.org/10.3389%2Ffchem.2022.1012605},
doi = {10.3389/fchem.2022.1012605}
}