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7,7’-(4,4-bis(2-ethylhexyl)-4h-cyclopenta[2,1-b:3,4-b’] dithiophene-2,6-diyl)bis(4-bromobenzo[c][1,2,5]thiadiazole)
Publication type: Journal Article
Publication date: 2021-12-23
DOI:
10.3390/M1310
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
2,6-Bis(benzo[c][1,2,5]thiadiazol-4-yl)-4H-cyclopenta[2,1-b:3,4-b’]dithiophenes are of interest for the synthesis of molecules which can be employed in optoelectronic devices. In this communication, 7,7’-(4,4-bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b’]dithiophene-2,6-diyl)bis(4-bromobenzo[c][1,2,5]thiadiazole) was obtained by direct C–H cross-coupling of 4,7-dibromobenzo[c][1,2,5]thiadiazole with 4,4-bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b’]dithiophene in the presence of palladium(II)acetate and potassium pivalate. The structure of newly synthesized compound was established by means of elemental analysis, high-resolution mass spectrometry, 1H, 13C NMR, IR and UV spectroscopy.
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Gudim N. S. et al. 7,7’-(4,4-bis(2-ethylhexyl)-4h-cyclopenta[2,1-b:3,4-b’] dithiophene-2,6-diyl)bis(4-bromobenzo[c][1,2,5]thiadiazole) // MolBank. 2021. Vol. 2022. No. 1. p. M1310.
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Gudim N. S., Knyazeva E. A., Rakitin O. A. 7,7’-(4,4-bis(2-ethylhexyl)-4h-cyclopenta[2,1-b:3,4-b’] dithiophene-2,6-diyl)bis(4-bromobenzo[c][1,2,5]thiadiazole) // MolBank. 2021. Vol. 2022. No. 1. p. M1310.
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TY - JOUR
DO - 10.3390/M1310
UR - https://www.mdpi.com/1422-8599/2022/1/M1310
TI - 7,7’-(4,4-bis(2-ethylhexyl)-4h-cyclopenta[2,1-b:3,4-b’] dithiophene-2,6-diyl)bis(4-bromobenzo[c][1,2,5]thiadiazole)
T2 - MolBank
AU - Gudim, Nikita S
AU - Knyazeva, Ekaterina A
AU - Rakitin, Oleg A.
PY - 2021
DA - 2021/12/23
PB - MDPI
SP - M1310
IS - 1
VL - 2022
SN - 1422-8599
ER -
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@article{2021_Gudim,
author = {Nikita S Gudim and Ekaterina A Knyazeva and Oleg A. Rakitin},
title = {7,7’-(4,4-bis(2-ethylhexyl)-4h-cyclopenta[2,1-b:3,4-b’] dithiophene-2,6-diyl)bis(4-bromobenzo[c][1,2,5]thiadiazole)},
journal = {MolBank},
year = {2021},
volume = {2022},
publisher = {MDPI},
month = {dec},
url = {https://www.mdpi.com/1422-8599/2022/1/M1310},
number = {1},
pages = {M1310},
doi = {10.3390/M1310}
}
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MLA
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Gudim, Nikita S., et al. “7,7’-(4,4-bis(2-ethylhexyl)-4h-cyclopenta[2,1-b:3,4-b’] dithiophene-2,6-diyl)bis(4-bromobenzo[c][1,2,5]thiadiazole).” MolBank, vol. 2022, no. 1, Dec. 2021, p. M1310. https://www.mdpi.com/1422-8599/2022/1/M1310.