Open Access
Batteries, volume 7, issue 4, pages 75
Perovskite Solid-State Electrolytes for Lithium Metal Batteries
Shuo Yan
1
,
Chae-Ho Yim
2
,
Vladimir Pankov
2
,
Mackenzie Bauer
2
,
Elena A. Baranova
1
,
Arnaud Weck
3
,
Ali Merati
2
,
Yaser Abu-Lebdeh
2
1
Department of Chemical and Biological Engineering, Faculty of Engineering, University of Ottawa, 800 King Edward Ave., Ottawa, ON K1N 6N5, Canada
|
2
National Research Council of Canada, 1200 Montreal Rd., Ottawa, ON K1A 0R6, Canada
|
3
Department of Mechanical Engineering, Faculty of Engineering, University of Ottawa, 800 King Edward Ave., Ottawa, ON K1N 6N5, Canada
|
Publication type: Journal Article
Publication date: 2021-11-07
Electrochemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Abstract
Solid-state lithium metal batteries (LMBs) have become increasingly important in recent years due to their potential to offer higher energy density and enhanced safety compared to conventional liquid electrolyte-based lithium-ion batteries (LIBs). However, they require highly functional solid-state electrolytes (SSEs) and, therefore, many inorganic materials such as oxides of perovskite La2/3−xLi3xTiO3 (LLTO) and garnets La3Li7Zr2O12 (LLZO), sulfides Li10GeP2S12 (LGPS), and phosphates Li1+xAlxTi2−x(PO4)3x (LATP) are under investigation. Among these oxide materials, LLTO exhibits superior safety, wider electrochemical window (8 V vs. Li/Li+), and higher bulk conductivity values reaching in excess of 10−3 S cm−1 at ambient temperature, which is close to organic liquid-state electrolytes presently used in LIBs. However, recent studies focus primarily on composite or hybrid electrolytes that mix LLTO with organic polymeric materials. There are scarce studies of pure (100%) LLTO electrolytes in solid-state LMBs and there is a need to shed more light on this type of electrolyte and its potential for LMBs. Therefore, in our review, we first elaborated on the structure/property relationship between compositions of perovskites and their ionic conductivities. We then summarized current issues and some successful attempts for the fabrication of pure LLTO electrolytes. Their electrochemical and battery performances were also presented. We focused on tape casting as an effective method to prepare pure LLTO thin films that are compatible and can be easily integrated into existing roll-to-roll battery manufacturing processes. This review intends to shed some light on the design and manufacturing of LLTO for all-ceramic electrolytes towards safer and higher power density solid-state LMBs.
Top-30
Citations by journals
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ACS applied materials & interfaces
2 publications, 6.67%
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Materials
2 publications, 6.67%
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Journal of Power Sources
2 publications, 6.67%
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Journal of Alloys and Compounds
2 publications, 6.67%
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Advanced Science
2 publications, 6.67%
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Frontiers in Chemistry
1 publication, 3.33%
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Journal of Energy Storage
1 publication, 3.33%
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Advanced Energy Materials
1 publication, 3.33%
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Zeitschrift fur Kristallographie - Crystalline Materials
1 publication, 3.33%
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Advanced Functional Materials
1 publication, 3.33%
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Physica B: Condensed Matter
1 publication, 3.33%
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Acta Physica Sinica
1 publication, 3.33%
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Physical Chemistry Chemical Physics
1 publication, 3.33%
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Batteries
1 publication, 3.33%
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International Journal of Energy Research
1 publication, 3.33%
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Solid State Ionics
1 publication, 3.33%
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Journal of Materials Chemistry A
1 publication, 3.33%
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ACS Nano
1 publication, 3.33%
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Energy Materials
1 publication, 3.33%
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Chemosensors
1 publication, 3.33%
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Russian Chemical Reviews
1 publication, 3.33%
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Chemistry of Materials
1 publication, 3.33%
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2
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Citations by publishers
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1
2
3
4
5
6
7
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Elsevier
7 publications, 23.33%
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American Chemical Society (ACS)
4 publications, 13.33%
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Multidisciplinary Digital Publishing Institute (MDPI)
4 publications, 13.33%
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Wiley
4 publications, 13.33%
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Royal Society of Chemistry (RSC)
2 publications, 6.67%
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Frontiers Media S.A.
1 publication, 3.33%
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Walter de Gruyter
1 publication, 3.33%
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Chinese Physical Society
1 publication, 3.33%
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Hindawi Limited
1 publication, 3.33%
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OAE Publishing Inc.
1 publication, 3.33%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 3.33%
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1
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Yan S. et al. Perovskite Solid-State Electrolytes for Lithium Metal Batteries // Batteries. 2021. Vol. 7. No. 4. p. 75.
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Yan S., Yim C., Pankov V., Bauer M., Baranova E. A., Weck A., Merati A., Abu-Lebdeh Y. Perovskite Solid-State Electrolytes for Lithium Metal Batteries // Batteries. 2021. Vol. 7. No. 4. p. 75.
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TY - JOUR
DO - 10.3390/batteries7040075
UR - https://doi.org/10.3390/batteries7040075
TI - Perovskite Solid-State Electrolytes for Lithium Metal Batteries
T2 - Batteries
AU - Yan, Shuo
AU - Pankov, Vladimir
AU - Bauer, Mackenzie
AU - Weck, Arnaud
AU - Merati, Ali
AU - Abu-Lebdeh, Yaser
AU - Yim, Chae-Ho
AU - Baranova, Elena A.
PY - 2021
DA - 2021/11/07 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 75
IS - 4
VL - 7
SN - 2313-0105
ER -
Cite this
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@article{2021_Yan,
author = {Shuo Yan and Vladimir Pankov and Mackenzie Bauer and Arnaud Weck and Ali Merati and Yaser Abu-Lebdeh and Chae-Ho Yim and Elena A. Baranova},
title = {Perovskite Solid-State Electrolytes for Lithium Metal Batteries},
journal = {Batteries},
year = {2021},
volume = {7},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {nov},
url = {https://doi.org/10.3390/batteries7040075},
number = {4},
pages = {75},
doi = {10.3390/batteries7040075}
}
Cite this
MLA
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Yan, Shuo, et al. “Perovskite Solid-State Electrolytes for Lithium Metal Batteries.” Batteries, vol. 7, no. 4, Nov. 2021, p. 75. https://doi.org/10.3390/batteries7040075.