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Catalysts, volume 13, issue 2, pages 273

Selectivity Control of CO2 Reduction over Pt/g-C3N4 Photocatalysts under Visible Light

Publication typeJournal Article
Publication date2023-01-25
Journal: Catalysts
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor3.9
ISSN20734344, 20734344
Catalysis
Physical and Theoretical Chemistry
General Environmental Science
Abstract

Photocatalysts based on g-C3N4 have been investigated in the CO2 reduction reaction under visible light irradiation (λ = 397, 427, 452 nm). Photocatalysts were prepared by melamine calcination at 500–600 °C with further platinum deposition (0.1–1.0 wt.%). The effect of the preparation conditions of g-C3N4 and the method of platinum deposition on the physicochemical properties and activity of photocatalysts was studied. The photocatalysts were investigated by X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, X-ray diffraction, high resolution transmission electron microscopy, UV-Vis spectroscopy, and low temperature nitrogen adsorption techniques. It has been found that the efficiency of CO2 reduction is governed by the surface area of g-C3N4 and the presence of platinum in the metallic state, while the optimal content of platinum is 0.5 wt. %. The highest rate of CO2 reduction achieved over Pt/g-C3N4 photocatalyst is 13.2 µmol h−1 g−1 (397 nm), which exceeds the activity of pristine g-C3N4 by 7 times. The most active photocatalysts was prepared by calcining melamine in air at 600 °C, followed by modification with platinum (0.5 wt.%).

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Saraev A. A. et al. Selectivity Control of CO2 Reduction over Pt/g-C3N4 Photocatalysts under Visible Light // Catalysts. 2023. Vol. 13. No. 2. p. 273.
GOST all authors (up to 50) Copy
Saraev A. A., Kurenkova A., Zhurenok A. V., Gerasimov E., Kozlova E. A. Selectivity Control of CO2 Reduction over Pt/g-C3N4 Photocatalysts under Visible Light // Catalysts. 2023. Vol. 13. No. 2. p. 273.
RIS |
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RIS Copy
TY - JOUR
DO - 10.3390/catal13020273
UR - https://doi.org/10.3390/catal13020273
TI - Selectivity Control of CO2 Reduction over Pt/g-C3N4 Photocatalysts under Visible Light
T2 - Catalysts
AU - Saraev, Andrey A.
AU - Kurenkova, Anna
AU - Zhurenok, Angelina V
AU - Gerasimov, Evgeny
AU - Kozlova, Ekaterina A.
PY - 2023
DA - 2023/01/25 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 273
IS - 2
VL - 13
SN - 2073-4344
SN - 2073-4344
ER -
BibTex |
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BibTex Copy
@article{2023_Saraev,
author = {Andrey A. Saraev and Anna Kurenkova and Angelina V Zhurenok and Evgeny Gerasimov and Ekaterina A. Kozlova},
title = {Selectivity Control of CO2 Reduction over Pt/g-C3N4 Photocatalysts under Visible Light},
journal = {Catalysts},
year = {2023},
volume = {13},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {jan},
url = {https://doi.org/10.3390/catal13020273},
number = {2},
pages = {273},
doi = {10.3390/catal13020273}
}
MLA
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MLA Copy
Saraev, Andrey A., et al. “Selectivity Control of CO2 Reduction over Pt/g-C3N4 Photocatalysts under Visible Light.” Catalysts, vol. 13, no. 2, Jan. 2023, p. 273. https://doi.org/10.3390/catal13020273.
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