Open Access
Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen Donors
Publication type: Journal Article
Publication date: 2018-12-19
Catalysis
Physical and Theoretical Chemistry
Abstract
Hydrogen transfer reactions have exceptional importance, due to their applicability in numerous synthetic pathways, with academic as well as industrial relevance. The most important transformations are, e.g., reduction, ring-closing, stereoselective reactions, and the synthesis of heterocycles. The present review provides insights into the hydrogen transfer reactions in the condensed phase in the presence of noble metals (Rh, Ru, Pd) as catalysts. Since the H-donor molecules (such as alcohols/ethers and amines (1°, 2°, 3°)) and the acceptor molecules (alkenes (C=C), alkynes (C≡C), and carbonyl (C=O) compounds) play a crucial role from mechanistic viewpoints, the present summary points out the key mechanistic differences with the interpretation of current contributions and the corresponding historical achievements as well.
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80
Total citations:
80
Citations from 2025:
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(16.25%)
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GOST
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Baráth E. Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen Donors // Catalysts. 2018. Vol. 8. No. 12. p. 671.
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Baráth E. Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen Donors // Catalysts. 2018. Vol. 8. No. 12. p. 671.
Cite this
RIS
Copy
TY - JOUR
DO - 10.3390/catal8120671
UR - https://doi.org/10.3390/catal8120671
TI - Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen Donors
T2 - Catalysts
AU - Baráth, Eszter
PY - 2018
DA - 2018/12/19
PB - MDPI
SP - 671
IS - 12
VL - 8
SN - 2073-4344
ER -
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BibTex (up to 50 authors)
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@article{2018_Baráth,
author = {Eszter Baráth},
title = {Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen Donors},
journal = {Catalysts},
year = {2018},
volume = {8},
publisher = {MDPI},
month = {dec},
url = {https://doi.org/10.3390/catal8120671},
number = {12},
pages = {671},
doi = {10.3390/catal8120671}
}
Cite this
MLA
Copy
Baráth, Eszter. “Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen Donors.” Catalysts, vol. 8, no. 12, Dec. 2018, p. 671. https://doi.org/10.3390/catal8120671.