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Crystals, volume 10, issue 12, pages 1130

Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior

Publication typeJournal Article
Publication date2020-12-11
Journal: Crystals
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor2.7
ISSN20734352, 01725076
Inorganic Chemistry
General Chemical Engineering
Condensed Matter Physics
General Materials Science
Abstract

The reaction of (NBu4)2Bzmal (where Bzmal2− is benzylmalonate dianion) with Co(OAc)2∙4H2O gives the [Co(Bzmal)(EtOH)(H2O)]n 2D-polymer (1). The addition of 2,2′-bipyridine (bpy) to the starting system results in the [Co(Bzmal)(bpy)2]·H2O·EtOH molecular complex (2). Their molecular and crystal structures were analyzed by single-crystal X-ray crystallography. An analysis of the static magnetic data supported by the SA-CASSCF/NEVPT2 calculations revealed the presence of easy-plane magnetic anisotropy in both complexes. The AC susceptibility data confirm that both complexes show a slow field-induced (HDC = 1000 Oe) magnetic relaxation behavior.

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Zorina-Tikhonova E. N. et al. Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior // Crystals. 2020. Vol. 10. No. 12. p. 1130.
GOST all authors (up to 50) Copy
Zorina-Tikhonova E. N., Matyukhina A., Skabitskiy I., Shmelev M. A., Korchagin D., Babeshkin K. A., Efimov N., Kiskin M. A., Eremenko I. L. Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior // Crystals. 2020. Vol. 10. No. 12. p. 1130.
RIS |
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RIS Copy
TY - JOUR
DO - 10.3390/cryst10121130
UR - https://doi.org/10.3390%2Fcryst10121130
TI - Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior
T2 - Crystals
AU - Skabitskiy, Ivan
AU - Matyukhina, Anna
AU - Efimov, Nikolay
AU - Zorina-Tikhonova, Ekaterina N.
AU - Shmelev, M. A.
AU - Korchagin, Denis
AU - Babeshkin, Konstantin A
AU - Kiskin, Mikhail A.
AU - Eremenko, Igor L.
PY - 2020
DA - 2020/12/11 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 1130
IS - 12
VL - 10
SN - 2073-4352
SN - 0172-5076
ER -
BibTex |
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BibTex Copy
@article{2020_Zorina-Tikhonova
author = {Ivan Skabitskiy and Anna Matyukhina and Nikolay Efimov and Ekaterina N. Zorina-Tikhonova and M. A. Shmelev and Denis Korchagin and Konstantin A Babeshkin and Mikhail A. Kiskin and Igor L. Eremenko},
title = {Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior},
journal = {Crystals},
year = {2020},
volume = {10},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {dec},
url = {https://doi.org/10.3390%2Fcryst10121130},
number = {12},
pages = {1130},
doi = {10.3390/cryst10121130}
}
MLA
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MLA Copy
Zorina-Tikhonova, Ekaterina N., et al. “Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior.” Crystals, vol. 10, no. 12, Dec. 2020, p. 1130. https://doi.org/10.3390%2Fcryst10121130.
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