Open Access
Crystals, volume 10, issue 12, pages 1130
Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior
Publication type: Journal Article
Publication date: 2020-12-11
Inorganic Chemistry
General Chemical Engineering
Condensed Matter Physics
General Materials Science
Abstract
The reaction of (NBu4)2Bzmal (where Bzmal2− is benzylmalonate dianion) with Co(OAc)2∙4H2O gives the [Co(Bzmal)(EtOH)(H2O)]n 2D-polymer (1). The addition of 2,2′-bipyridine (bpy) to the starting system results in the [Co(Bzmal)(bpy)2]·H2O·EtOH molecular complex (2). Their molecular and crystal structures were analyzed by single-crystal X-ray crystallography. An analysis of the static magnetic data supported by the SA-CASSCF/NEVPT2 calculations revealed the presence of easy-plane magnetic anisotropy in both complexes. The AC susceptibility data confirm that both complexes show a slow field-induced (HDC = 1000 Oe) magnetic relaxation behavior.
Citations by journals
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2
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Russian Chemical Bulletin
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Russian Chemical Bulletin
2 publications, 25%
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Journal of Structural Chemistry
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Journal of Structural Chemistry
1 publication, 12.5%
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Journal of Molecular Structure
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Journal of Molecular Structure
1 publication, 12.5%
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Molecules
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Molecules
1 publication, 12.5%
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New Journal of Chemistry
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New Journal of Chemistry
1 publication, 12.5%
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Crystal Growth and Design
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Crystal Growth and Design
1 publication, 12.5%
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Monatshefte fur Chemie
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Monatshefte fur Chemie
1 publication, 12.5%
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2
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Citations by publishers
1
2
3
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Springer Nature
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Springer Nature
3 publications, 37.5%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 12.5%
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Elsevier
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Elsevier
1 publication, 12.5%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 12.5%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 12.5%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 12.5%
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- We do not take into account publications that without a DOI.
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Zorina-Tikhonova E. N. et al. Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior // Crystals. 2020. Vol. 10. No. 12. p. 1130.
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Zorina-Tikhonova E. N., Matyukhina A., Skabitskiy I., Shmelev M. A., Korchagin D., Babeshkin K. A., Efimov N., Kiskin M. A., Eremenko I. L. Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior // Crystals. 2020. Vol. 10. No. 12. p. 1130.
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TY - JOUR
DO - 10.3390/cryst10121130
UR - https://doi.org/10.3390%2Fcryst10121130
TI - Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior
T2 - Crystals
AU - Skabitskiy, Ivan
AU - Matyukhina, Anna
AU - Efimov, Nikolay
AU - Zorina-Tikhonova, Ekaterina N.
AU - Shmelev, M. A.
AU - Korchagin, Denis
AU - Babeshkin, Konstantin A
AU - Kiskin, Mikhail A.
AU - Eremenko, Igor L.
PY - 2020
DA - 2020/12/11 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 1130
IS - 12
VL - 10
SN - 2073-4352
SN - 0172-5076
ER -
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@article{2020_Zorina-Tikhonova
author = {Ivan Skabitskiy and Anna Matyukhina and Nikolay Efimov and Ekaterina N. Zorina-Tikhonova and M. A. Shmelev and Denis Korchagin and Konstantin A Babeshkin and Mikhail A. Kiskin and Igor L. Eremenko},
title = {Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior},
journal = {Crystals},
year = {2020},
volume = {10},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {dec},
url = {https://doi.org/10.3390%2Fcryst10121130},
number = {12},
pages = {1130},
doi = {10.3390/cryst10121130}
}
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MLA
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Zorina-Tikhonova, Ekaterina N., et al. “Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior.” Crystals, vol. 10, no. 12, Dec. 2020, p. 1130. https://doi.org/10.3390%2Fcryst10121130.