Open Access
Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior
Publication type: Journal Article
Publication date: 2020-12-11
scimago Q2
wos Q2
SJR: 0.486
CiteScore: 5.0
Impact factor: 2.4
ISSN: 20734352, 01725076
Inorganic Chemistry
General Chemical Engineering
Condensed Matter Physics
General Materials Science
Abstract
The reaction of (NBu4)2Bzmal (where Bzmal2− is benzylmalonate dianion) with Co(OAc)2∙4H2O gives the [Co(Bzmal)(EtOH)(H2O)]n 2D-polymer (1). The addition of 2,2′-bipyridine (bpy) to the starting system results in the [Co(Bzmal)(bpy)2]·H2O·EtOH molecular complex (2). Their molecular and crystal structures were analyzed by single-crystal X-ray crystallography. An analysis of the static magnetic data supported by the SA-CASSCF/NEVPT2 calculations revealed the presence of easy-plane magnetic anisotropy in both complexes. The AC susceptibility data confirm that both complexes show a slow field-induced (HDC = 1000 Oe) magnetic relaxation behavior.
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13
Total citations:
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Citations from 2024:
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(38%)
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GOST
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Zorina-Tikhonova E. N. et al. Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior // Crystals. 2020. Vol. 10. No. 12. p. 1130.
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Zorina-Tikhonova E. N., Matyukhina A., Skabitskiy I., Shmelev M. A., Korchagin D., Babeshkin K. A., Efimov N., Kiskin M. A., Eremenko I. L. Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior // Crystals. 2020. Vol. 10. No. 12. p. 1130.
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TY - JOUR
DO - 10.3390/cryst10121130
UR - https://doi.org/10.3390/cryst10121130
TI - Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior
T2 - Crystals
AU - Zorina-Tikhonova, Ekaterina N.
AU - Matyukhina, Anna
AU - Skabitskiy, Ivan
AU - Shmelev, M. A.
AU - Korchagin, Denis
AU - Babeshkin, Konstantin A
AU - Efimov, Nikolay
AU - Kiskin, Mikhail A.
AU - Eremenko, Igor L.
PY - 2020
DA - 2020/12/11
PB - MDPI
SP - 1130
IS - 12
VL - 10
SN - 2073-4352
SN - 0172-5076
ER -
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BibTex (up to 50 authors)
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@article{2020_Zorina-Tikhonova,
author = {Ekaterina N. Zorina-Tikhonova and Anna Matyukhina and Ivan Skabitskiy and M. A. Shmelev and Denis Korchagin and Konstantin A Babeshkin and Nikolay Efimov and Mikhail A. Kiskin and Igor L. Eremenko},
title = {Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior},
journal = {Crystals},
year = {2020},
volume = {10},
publisher = {MDPI},
month = {dec},
url = {https://doi.org/10.3390/cryst10121130},
number = {12},
pages = {1130},
doi = {10.3390/cryst10121130}
}
Cite this
MLA
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Zorina-Tikhonova, Ekaterina N., et al. “Cobalt(II) Complexes Based on Benzylmalonate Anions Exhibiting Field-Induced Single-Ion Magnet Slow Relaxation Behavior.” Crystals, vol. 10, no. 12, Dec. 2020, p. 1130. https://doi.org/10.3390/cryst10121130.