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volume 13 issue 9 pages 1356

Reversible Transformations of Palladium–Indium Intermetallic Nanoparticles upon Repetitive Redox Treatments in H2/O2

Publication typeJournal Article
Publication date2023-09-08
scimago Q2
wos Q2
SJR0.486
CiteScore5.0
Impact factor2.4
ISSN20734352, 01725076
Inorganic Chemistry
General Chemical Engineering
Condensed Matter Physics
General Materials Science
Abstract

The transformations of chemical states and structures occurring in the PdIn/Al2O3 catalyst upon redox treatments in different gaseous atmospheres at different temperatures are addressed by an assortment of in situ bulk- (XRD) and surface-sensitive (XPS and DRIFTS CO) techniques. Any desired state of the catalyst between two opposite extremes of highly dispersed oxide species and regularly ordered PdIn intermetallic compound could be set in fully controlled and reversible ways by selecting appropriate conditions for the reductive treatment starting from the fully oxidized state. Since mutual conversions of multi-atomic Pdn centers into single-site Pd1 centers are involved in these transformations, the methodology could be used to find an optimum balance between the activity and selectivity of the catalytic system.

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Bukhtiyarov A. V. et al. Reversible Transformations of Palladium–Indium Intermetallic Nanoparticles upon Repetitive Redox Treatments in H2/O2 // Crystals. 2023. Vol. 13. No. 9. p. 1356.
GOST all authors (up to 50) Copy
Bukhtiyarov A. V., Panafidin M. A., Prosvirin I. P., Smirnova N. S., Markov P. V., Baeva G. N., Mashkovsky I. S., Bragina G. O., Vinokurov Z., Zubavichus Y. V., Bukhtiyarov V. I., Stakheev A. Yu. Reversible Transformations of Palladium–Indium Intermetallic Nanoparticles upon Repetitive Redox Treatments in H2/O2 // Crystals. 2023. Vol. 13. No. 9. p. 1356.
RIS |
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RIS Copy
TY - JOUR
DO - 10.3390/cryst13091356
UR - https://www.mdpi.com/2073-4352/13/9/1356
TI - Reversible Transformations of Palladium–Indium Intermetallic Nanoparticles upon Repetitive Redox Treatments in H2/O2
T2 - Crystals
AU - Bukhtiyarov, Andrey V
AU - Panafidin, Maxim A
AU - Prosvirin, Igor P.
AU - Smirnova, Nadezhda S
AU - Markov, Pavel V
AU - Baeva, Galina N
AU - Mashkovsky, Igor S
AU - Bragina, Galina O
AU - Vinokurov, Zahar
AU - Zubavichus, Yan V.
AU - Bukhtiyarov, Valerii I
AU - Stakheev, Alexander Yu
PY - 2023
DA - 2023/09/08
PB - MDPI
SP - 1356
IS - 9
VL - 13
SN - 2073-4352
SN - 0172-5076
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2023_Bukhtiyarov,
author = {Andrey V Bukhtiyarov and Maxim A Panafidin and Igor P. Prosvirin and Nadezhda S Smirnova and Pavel V Markov and Galina N Baeva and Igor S Mashkovsky and Galina O Bragina and Zahar Vinokurov and Yan V. Zubavichus and Valerii I Bukhtiyarov and Alexander Yu Stakheev},
title = {Reversible Transformations of Palladium–Indium Intermetallic Nanoparticles upon Repetitive Redox Treatments in H2/O2},
journal = {Crystals},
year = {2023},
volume = {13},
publisher = {MDPI},
month = {sep},
url = {https://www.mdpi.com/2073-4352/13/9/1356},
number = {9},
pages = {1356},
doi = {10.3390/cryst13091356}
}
MLA
Cite this
MLA Copy
Bukhtiyarov, Andrey V., et al. “Reversible Transformations of Palladium–Indium Intermetallic Nanoparticles upon Repetitive Redox Treatments in H2/O2.” Crystals, vol. 13, no. 9, Sep. 2023, p. 1356. https://www.mdpi.com/2073-4352/13/9/1356.