Open Access
Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(η2-BH4)2] Dichloromethane Solvate
Natalia Belkova
1
,
Igor Golub
1, 2
,
Evgenii Gutsul
1
,
Alexander Peregudov
1
,
Viktor Makhaev
3
,
Oleg Filippov
1
,
Lina Epstein
1
,
Andrea Rossin
4
,
Maurizio Peruzzini
4
,
Publication type: Journal Article
Publication date: 2017-10-20
scimago Q2
wos Q2
SJR: 0.486
CiteScore: 5.0
Impact factor: 2.4
ISSN: 20734352, 01725076
Inorganic Chemistry
General Chemical Engineering
Condensed Matter Physics
General Materials Science
Abstract
Bis(diphenylphosphino)methane copper(I) tetrahydroborate was synthesized by ligands exchange in bis(triphenylphosphine) copper(I) tetrahydroborate, and characterized by XRD, FTIR, NMR spectroscopy. According to XRD the title compound has dimeric structure, [(μ2-dppm)2Cu2(η2-BH4)2], and crystallizes as CH2Cl2 solvate in two polymorphic forms (orthorhombic, 1, and monoclinic, 2) The details of molecular geometry and the crystal-packing pattern in polymorphs were studied. The rare Twisted Boat-Boat conformation of the core Cu2P4C2 cycle in 1 is found being more stable than Boat-Boat conformation in 2.
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15
Total citations:
15
Citations from 2024:
3
(20%)
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GOST
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Belkova N. et al. Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(η2-BH4)2] Dichloromethane Solvate // Crystals. 2017. Vol. 7. No. 10. p. 318.
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Belkova N., Golub I., Gutsul E., Lyssenko K., Peregudov A., Makhaev V., Filippov O., Epstein L., Rossin A., Peruzzini M., Shubina E. Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(η2-BH4)2] Dichloromethane Solvate // Crystals. 2017. Vol. 7. No. 10. p. 318.
Cite this
RIS
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TY - JOUR
DO - 10.3390/cryst7100318
UR - https://doi.org/10.3390/cryst7100318
TI - Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(η2-BH4)2] Dichloromethane Solvate
T2 - Crystals
AU - Belkova, Natalia
AU - Golub, Igor
AU - Gutsul, Evgenii
AU - Lyssenko, Konstantin
AU - Peregudov, Alexander
AU - Makhaev, Viktor
AU - Filippov, Oleg
AU - Epstein, Lina
AU - Rossin, Andrea
AU - Peruzzini, Maurizio
AU - Shubina, Elena
PY - 2017
DA - 2017/10/20
PB - MDPI
SP - 318
IS - 10
VL - 7
SN - 2073-4352
SN - 0172-5076
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Belkova,
author = {Natalia Belkova and Igor Golub and Evgenii Gutsul and Konstantin Lyssenko and Alexander Peregudov and Viktor Makhaev and Oleg Filippov and Lina Epstein and Andrea Rossin and Maurizio Peruzzini and Elena Shubina},
title = {Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(η2-BH4)2] Dichloromethane Solvate},
journal = {Crystals},
year = {2017},
volume = {7},
publisher = {MDPI},
month = {oct},
url = {https://doi.org/10.3390/cryst7100318},
number = {10},
pages = {318},
doi = {10.3390/cryst7100318}
}
Cite this
MLA
Copy
Belkova, Natalia, et al. “Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(η2-BH4)2] Dichloromethane Solvate.” Crystals, vol. 7, no. 10, Oct. 2017, p. 318. https://doi.org/10.3390/cryst7100318.