Open Access
International Journal of Molecular Sciences, volume 23, issue 5, pages 2763
Thermal Mapping of Self-Promoted Calcium Carbide Reactions for Performing Energy-Economic Processes
Publication type: Journal Article
Publication date: 2022-03-02
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.6
ISSN: 16616596, 14220067
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Computer Science Applications
Spectroscopy
Molecular Biology
General Medicine
Abstract
The syntheses of various chemical compounds require heating. The intrinsic release of heat in exothermic processes is a valuable heat source that is not effectively used in many reactions. In this work, we assessed the released heat during the hydrolysis of an energy-rich compound, calcium carbide, and explored the possibility of its usage. Temperature profiles of carbide hydrolysis were recorded, and it was found that the heat release depended on the cosolvent and water/solvent ratio. Thus, the release of heat can be controlled and adjusted. To monitor the released heat, a special tube-in-tube reactor was assembled using joining part 3D-printed with nylon. The thermal effect of the reaction was estimated using a thermoimaging IR monitor. It was found that the kinetics of heat release are different when using mixtures of water with different solvents, and the maximum achievable temperature depends on the type of solvent and the amount of water and carbide. The possibility of using the heat released during carbide hydrolysis to initiate a chemical reaction was tested using a hydrothiolation reaction—the nucleophilic addition of thiols to acetylene. In a model experiment, the yield of the desired product with the use of heat from carbide hydrolysis was 89%, compared to 30% in this intrinsic heating, which was neglected.
Citations by journals
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1
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Journal of Chemical Education
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Journal of Chemical Education
1 publication, 25%
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Russian Chemical Reviews
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Russian Chemical Reviews
1 publication, 25%
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European Journal of Organic Chemistry
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European Journal of Organic Chemistry
1 publication, 25%
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Green Chemistry
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Green Chemistry
1 publication, 25%
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1
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Citations by publishers
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1
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 25%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 25%
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Wiley
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Wiley
1 publication, 25%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 25%
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1
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- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Rodygin K. S. et al. Thermal Mapping of Self-Promoted Calcium Carbide Reactions for Performing Energy-Economic Processes // International Journal of Molecular Sciences. 2022. Vol. 23. No. 5. p. 2763.
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Rodygin K. S., Lotsman K. A., Erokhin K. S., Korabelnikova V. A., Ananikov V. P. Thermal Mapping of Self-Promoted Calcium Carbide Reactions for Performing Energy-Economic Processes // International Journal of Molecular Sciences. 2022. Vol. 23. No. 5. p. 2763.
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TY - JOUR
DO - 10.3390/ijms23052763
UR - https://doi.org/10.3390%2Fijms23052763
TI - Thermal Mapping of Self-Promoted Calcium Carbide Reactions for Performing Energy-Economic Processes
T2 - International Journal of Molecular Sciences
AU - Rodygin, Konstantin S
AU - Korabelnikova, Viktoria A
AU - Lotsman, Kristina A
AU - Erokhin, Kirill S
AU - Ananikov, Valentine P.
PY - 2022
DA - 2022/03/02 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 2763
IS - 5
VL - 23
SN - 1661-6596
SN - 1422-0067
ER -
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@article{2022_Rodygin,
author = {Konstantin S Rodygin and Viktoria A Korabelnikova and Kristina A Lotsman and Kirill S Erokhin and Valentine P. Ananikov},
title = {Thermal Mapping of Self-Promoted Calcium Carbide Reactions for Performing Energy-Economic Processes},
journal = {International Journal of Molecular Sciences},
year = {2022},
volume = {23},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {mar},
url = {https://doi.org/10.3390%2Fijms23052763},
number = {5},
pages = {2763},
doi = {10.3390/ijms23052763}
}
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MLA
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Rodygin, Konstantin S., et al. “Thermal Mapping of Self-Promoted Calcium Carbide Reactions for Performing Energy-Economic Processes.” International Journal of Molecular Sciences, vol. 23, no. 5, Mar. 2022, p. 2763. https://doi.org/10.3390%2Fijms23052763.
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