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volume 6 issue 2 pages 38

The melt of Sodium Nitrate as a medium for the synthesis of Fluorides

Publication typeJournal Article
Publication date2018-03-29
scimago Q2
wos Q2
SJR0.509
CiteScore4.1
Impact factor3.0
ISSN23046740
Inorganic Chemistry
Abstract

The preparation of NaLnF4 complexes, LnF3 (Ln = La, Ce, Y) rare earth binary fluorides, CaF2 and SrF2 alkali earth fluorides, as well as mixtures of these compounds from their nitrates dissolved in molten NaNO3 has been studied in order to select the ideal solvent for fluoride synthesis by spontaneous crystallization from flux. Sodium fluoride (NaF) was used as a fluorinating agent. The results of our experiments have confirmed that NaNO3 melt is one of the most promising media for precipitating said inorganic fluoride materials within a broad temperature range (300–500 °С). Also, in contrast with precipitation/co-precipitation from aqueous solutions, our syntheses have resulted in obtaining equilibrium phases only.

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GOST Copy
P. P. Fedorov P. P. F. et al. The melt of Sodium Nitrate as a medium for the synthesis of Fluorides // Inorganics. 2018. Vol. 6. No. 2. p. 38.
GOST all authors (up to 50) Copy
P. P. Fedorov P. P. F., Mayakova M., Alexandrov A., Alexandrov A. A., Voronov V., Kuznetsov S., Baranchikov A., Ivanov V., Ivanov V. K. The melt of Sodium Nitrate as a medium for the synthesis of Fluorides // Inorganics. 2018. Vol. 6. No. 2. p. 38.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.3390/inorganics6020038
UR - https://www.mdpi.com/2304-6740/6/2/38
TI - The melt of Sodium Nitrate as a medium for the synthesis of Fluorides
T2 - Inorganics
AU - P. P. Fedorov, P. P. Fedorov
AU - Mayakova, Mariya
AU - Alexandrov, Alexander
AU - Alexandrov, Alexander A
AU - Voronov, Valery
AU - Kuznetsov, Sergey
AU - Baranchikov, Alexander
AU - Ivanov, Vladimir
AU - Ivanov, Vladimir K.
PY - 2018
DA - 2018/03/29
PB - MDPI
SP - 38
IS - 2
VL - 6
SN - 2304-6740
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_P. P. Fedorov,
author = {P. P. Fedorov P. P. Fedorov and Mariya Mayakova and Alexander Alexandrov and Alexander A Alexandrov and Valery Voronov and Sergey Kuznetsov and Alexander Baranchikov and Vladimir Ivanov and Vladimir K. Ivanov},
title = {The melt of Sodium Nitrate as a medium for the synthesis of Fluorides},
journal = {Inorganics},
year = {2018},
volume = {6},
publisher = {MDPI},
month = {mar},
url = {https://www.mdpi.com/2304-6740/6/2/38},
number = {2},
pages = {38},
doi = {10.3390/inorganics6020038}
}
MLA
Cite this
MLA Copy
P. P. Fedorov, P. P. Fedorov, et al. “The melt of Sodium Nitrate as a medium for the synthesis of Fluorides.” Inorganics, vol. 6, no. 2, Mar. 2018, p. 38. https://www.mdpi.com/2304-6740/6/2/38.