Open Access
Open access
volume 19 issue 11 pages 635

Oceanalin B, a Hybrid α,ω-Bifunctionalized Sphingoid Tetrahydroisoquinoline β-Glycoside from the Marine Sponge Oceanapia sp.

Tatyana N Makarieva 1
Alla G. Guzii 1
Valentin A Stonik 1
Tadeusz F Molinski 2
Publication typeJournal Article
Publication date2021-11-12
scimago Q1
wos Q1
SJR1.030
CiteScore10.1
Impact factor5.4
ISSN16603397
PubMed ID:  34822506
Drug Discovery
Pharmaceutical Science
Pharmacology, Toxicology and Pharmaceutics (miscellaneous)
Abstract

Oceanalin B (1), an α,ω-bipolar natural product belonging to a rare family of sphingoid tetrahydoisoquinoline β-glycosides, was isolated from the EtOH extract of the lyophilized marine sponge Oceanapia sp. as the second member of the series after oceanalin A (2) from the same animal. The compounds are of particular interest due to their biogenetically unexpected structures as well as their biological activities. The structure and absolute stereochemistry of 1 as a α,ω-bifunctionalized sphingoid tetrahydroisoquinoline β-glycoside was elucidated using NMR, CD and MS spectral analysis and chemical degradation. Oceanalin B exhibited in vitro antifungal activity against Candidaglabrata with a MIC of 25 μg/mL.

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GOST |
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GOST Copy
Makarieva T. N. et al. Oceanalin B, a Hybrid α,ω-Bifunctionalized Sphingoid Tetrahydroisoquinoline β-Glycoside from the Marine Sponge Oceanapia sp. // Marine Drugs. 2021. Vol. 19. No. 11. p. 635.
GOST all authors (up to 50) Copy
Makarieva T. N., Ivanchina N. V., Dmitrenok P. S., Guzii A. G., Stonik V. A., Dalisay D. S., Molinski T. F. Oceanalin B, a Hybrid α,ω-Bifunctionalized Sphingoid Tetrahydroisoquinoline β-Glycoside from the Marine Sponge Oceanapia sp. // Marine Drugs. 2021. Vol. 19. No. 11. p. 635.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.3390/md19110635
UR - https://doi.org/10.3390/md19110635
TI - Oceanalin B, a Hybrid α,ω-Bifunctionalized Sphingoid Tetrahydroisoquinoline β-Glycoside from the Marine Sponge Oceanapia sp.
T2 - Marine Drugs
AU - Makarieva, Tatyana N
AU - Ivanchina, Natalia V.
AU - Dmitrenok, Pavel S
AU - Guzii, Alla G.
AU - Stonik, Valentin A
AU - Dalisay, Doralyn S.
AU - Molinski, Tadeusz F
PY - 2021
DA - 2021/11/12
PB - MDPI
SP - 635
IS - 11
VL - 19
PMID - 34822506
SN - 1660-3397
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Makarieva,
author = {Tatyana N Makarieva and Natalia V. Ivanchina and Pavel S Dmitrenok and Alla G. Guzii and Valentin A Stonik and Doralyn S. Dalisay and Tadeusz F Molinski},
title = {Oceanalin B, a Hybrid α,ω-Bifunctionalized Sphingoid Tetrahydroisoquinoline β-Glycoside from the Marine Sponge Oceanapia sp.},
journal = {Marine Drugs},
year = {2021},
volume = {19},
publisher = {MDPI},
month = {nov},
url = {https://doi.org/10.3390/md19110635},
number = {11},
pages = {635},
doi = {10.3390/md19110635}
}
MLA
Cite this
MLA Copy
Makarieva, Tatyana N., et al. “Oceanalin B, a Hybrid α,ω-Bifunctionalized Sphingoid Tetrahydroisoquinoline β-Glycoside from the Marine Sponge Oceanapia sp..” Marine Drugs, vol. 19, no. 11, Nov. 2021, p. 635. https://doi.org/10.3390/md19110635.