Open Access
Membranes, volume 12, issue 3, pages 316
Ionomers Based on Addition and Ring Opening Metathesis Polymerized 5‐Phenyl‐2‐norbornene as a Membrane Material for Ionic Actuators
Morozov Oleg
1
,
Ivanchenko Anna V
1
,
Shachneva Svetlana S
2
,
Bermeshev M.V.
3
,
Bulgakov Boris A
1
,
Publication type: Journal Article
Publication date: 2022-03-10
PubMed ID:
35323790
Process Chemistry and Technology
Chemical Engineering (miscellaneous)
Filtration and Separation
Abstract
Two types of poly(5-phenyl-2-norbornene) were synthesized via ring opening metathesis and addition polymerization. The polymers sulfonation reaction under homogeneous conditions resulted in ionomer with high sulfonation degree up to 79% (IEC 3.36 meq/g). The prepared ionomer was characterized by DSC, GPC, 1H NMR and FT-IR. Polymers for electromechanical applications soluble in common polar organic solvents were obtained by replacing proton of sulfonic group with imidazolium and 1-methylimidazlium. Membranes were prepared using the above-mentioned polymers and 1-ethyl-3-methylimidazolium tetrafluoroborate (EMImBF4), as well as mixtures with polyvinylidene fluoride (PVDF). Mechanical, morphological, and conductive properties of the membranes were examined by tensile testing, SEM, and impedance spectroscopy, respectively. Dry and air-stable actuators with electrodes based on SWCNT were fabricated via hot-pressing. Actuators with membranes based on methylimidazolium containing ionomers outperformed classical bucky gel actuator and demonstrated high strain (up to 1.14%) and generated stress (up to 1.21 MPa) under low voltage of 2 V.
Citations by journals
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1
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Membranes
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Membranes
1 publication, 33.33%
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Polymers
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Polymers
1 publication, 33.33%
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ChemElectroChem
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ChemElectroChem
1 publication, 33.33%
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1
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Citations by publishers
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1
2
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 66.67%
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Wiley
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Wiley
1 publication, 33.33%
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1
2
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Morozov O. et al. Ionomers Based on Addition and Ring Opening Metathesis Polymerized 5‐Phenyl‐2‐norbornene as a Membrane Material for Ionic Actuators // Membranes. 2022. Vol. 12. No. 3. p. 316.
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Morozov O., Babkin A. V., Ivanchenko A. V., Shachneva S. S., Nechausov S. S., Alentiev D. A., Bermeshev M., Bulgakov B. A., Kepman A. V. Ionomers Based on Addition and Ring Opening Metathesis Polymerized 5‐Phenyl‐2‐norbornene as a Membrane Material for Ionic Actuators // Membranes. 2022. Vol. 12. No. 3. p. 316.
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TY - JOUR
DO - 10.3390/membranes12030316
UR - https://doi.org/10.3390%2Fmembranes12030316
TI - Ionomers Based on Addition and Ring Opening Metathesis Polymerized 5‐Phenyl‐2‐norbornene as a Membrane Material for Ionic Actuators
T2 - Membranes
AU - Babkin, Alexander V
AU - Ivanchenko, Anna V
AU - Shachneva, Svetlana S
AU - Nechausov, Sergey S
AU - Bulgakov, Boris A
AU - Kepman, Alexey V
AU - Morozov, Oleg
AU - Alentiev, Dmitry A
AU - Bermeshev, M.V.
PY - 2022
DA - 2022/03/10 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 316
IS - 3
VL - 12
PMID - 35323790
SN - 2077-0375
ER -
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@article{2022_Morozov,
author = {Alexander V Babkin and Anna V Ivanchenko and Svetlana S Shachneva and Sergey S Nechausov and Boris A Bulgakov and Alexey V Kepman and Oleg Morozov and Dmitry A Alentiev and M.V. Bermeshev},
title = {Ionomers Based on Addition and Ring Opening Metathesis Polymerized 5‐Phenyl‐2‐norbornene as a Membrane Material for Ionic Actuators},
journal = {Membranes},
year = {2022},
volume = {12},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {mar},
url = {https://doi.org/10.3390%2Fmembranes12030316},
number = {3},
pages = {316},
doi = {10.3390/membranes12030316}
}
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MLA
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Morozov, Oleg, et al. “Ionomers Based on Addition and Ring Opening Metathesis Polymerized 5‐Phenyl‐2‐norbornene as a Membrane Material for Ionic Actuators.” Membranes, vol. 12, no. 3, Mar. 2022, p. 316. https://doi.org/10.3390%2Fmembranes12030316.