Open Access
Metals, volume 11, issue 2, pages 321
Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone
Publication type: Journal Article
Publication date: 2021-02-12
Metals and Alloys
General Materials Science
Abstract
Research into the solvent extraction of iron(III) from a chloride solution after bauxite HCl leaching by neutral oxygen-containing extractants and their mixtures were studied and the iron(III) extraction degree from chloride solutions using alcohols is presented. The effect of dilution of alcohol with a ketone by an extraction mixture in relation to its effectiveness was investigated. The iron(III) was efficiently extracted by the mixture of 1-octanol and 1-decanol (70%) with 2-undecanone (30%) from hydrochloric bauxite leach liquor at an O:A ratio = 2-4:1 at an iron(III) concentration of 7.4 g/L and 6 M HCl. For the removal of iron-containing organic phase from impurities (Al, Ca, Cr) that are co-extracted with iron(III), we used two step scrubbing at O:A = 5:1 by 7 M HCl as a scrub solution. The iron(III) stripping at the O:A ratio is shown. Using counter-current cascade of extractors, it was possible to obtain an FeCl3 solution with the iron(III) content of 90.5 g/L and total impurities less than 50 mg/L.
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Citations by publishers
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6
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Multidisciplinary Digital Publishing Institute (MDPI)
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6 publications, 50%
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Springer Nature
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2 publications, 16.67%
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Elsevier
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1 publication, 8.33%
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ASM International
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ASM International
1 publication, 8.33%
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Taylor & Francis
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Taylor & Francis
1 publication, 8.33%
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Veterinary World
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Veterinary World, 1, 8.33%
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1 publication, 8.33%
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6
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Sokolov A., Valeev D., Kasikov A. Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone // Metals. 2021. Vol. 11. No. 2. p. 321.
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Sokolov A., Valeev D., Kasikov A. Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone // Metals. 2021. Vol. 11. No. 2. p. 321.
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TY - JOUR
DO - 10.3390/met11020321
UR - https://doi.org/10.3390%2Fmet11020321
TI - Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone
T2 - Metals
AU - Sokolov, Artem
AU - Valeev, Dmitry
AU - Kasikov, Aleksandr
PY - 2021
DA - 2021/02/12 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 321
IS - 2
VL - 11
SN - 2075-4701
ER -
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@article{2021_Sokolov,
author = {Artem Sokolov and Dmitry Valeev and Aleksandr Kasikov},
title = {Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone},
journal = {Metals},
year = {2021},
volume = {11},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {feb},
url = {https://doi.org/10.3390%2Fmet11020321},
number = {2},
pages = {321},
doi = {10.3390/met11020321}
}
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Sokolov, Artem, et al. “Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone.” Metals, vol. 11, no. 2, Feb. 2021, p. 321. https://doi.org/10.3390%2Fmet11020321.