Open Access
Electrochemical Properties and Structure of Multi-Ferrocenyl Phosphorus Thioesters
Zilya Yamaleeva
1
,
Kamil Ivshin
2
,
Alyona Lakomkina
1
,
Ilya Bezkishko
1
,
Aleksandr Kononov
1
,
Oleg Sinyashin
1
,
Olga Kataeva
1
,
Publication type: Journal Article
Publication date: 2020-02-19
PubMed ID:
32093122
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
The reaction of triferrocenylthiophosphite with elemental sulfur leads to triferrocenyltetrathiophosphate. The molecule of tetrathiophosphate adopts propeller-like all synclinal-conformation of the ferrocenyl fragments respective to the P=S bond. All ferrocenyl groups have nearly ideal eclipsed conformation of the cyclopentadienyl fragments. The Fc3S3P (1), Fc3S3P=O, (2) and Fc3S3P=S (3) demonstrate three reversible and well-separated ferrocenyl-based redox events. The electronic structures of 1–3 have been studied quantum-chemically; the energies and composition of frontier orbitals have been calculated.
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7
Total citations:
7
Citations from 2024:
1
(14%)
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GOST
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Shekurov R. P. et al. Electrochemical Properties and Structure of Multi-Ferrocenyl Phosphorus Thioesters // Molecules. 2020. Vol. 25. No. 4. p. 939.
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Shekurov R. P., Khrizanforov M., Gerasimova T., Yamaleeva Z., Ivshin K., Lakomkina A., Bezkishko I., Kononov A., Sinyashin O., Budnikova Y. H., Kataeva O., Miluykov V. Electrochemical Properties and Structure of Multi-Ferrocenyl Phosphorus Thioesters // Molecules. 2020. Vol. 25. No. 4. p. 939.
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RIS
Copy
TY - JOUR
DO - 10.3390/molecules25040939
UR - https://doi.org/10.3390/molecules25040939
TI - Electrochemical Properties and Structure of Multi-Ferrocenyl Phosphorus Thioesters
T2 - Molecules
AU - Shekurov, Ruslan P
AU - Khrizanforov, Mikhail
AU - Gerasimova, Tatiana
AU - Yamaleeva, Zilya
AU - Ivshin, Kamil
AU - Lakomkina, Alyona
AU - Bezkishko, Ilya
AU - Kononov, Aleksandr
AU - Sinyashin, Oleg
AU - Budnikova, Yulia H.
AU - Kataeva, Olga
AU - Miluykov, Vasili
PY - 2020
DA - 2020/02/19
PB - MDPI
SP - 939
IS - 4
VL - 25
PMID - 32093122
SN - 1420-3049
ER -
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BibTex (up to 50 authors)
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@article{2020_Shekurov,
author = {Ruslan P Shekurov and Mikhail Khrizanforov and Tatiana Gerasimova and Zilya Yamaleeva and Kamil Ivshin and Alyona Lakomkina and Ilya Bezkishko and Aleksandr Kononov and Oleg Sinyashin and Yulia H. Budnikova and Olga Kataeva and Vasili Miluykov},
title = {Electrochemical Properties and Structure of Multi-Ferrocenyl Phosphorus Thioesters},
journal = {Molecules},
year = {2020},
volume = {25},
publisher = {MDPI},
month = {feb},
url = {https://doi.org/10.3390/molecules25040939},
number = {4},
pages = {939},
doi = {10.3390/molecules25040939}
}
Cite this
MLA
Copy
Shekurov, Ruslan P., et al. “Electrochemical Properties and Structure of Multi-Ferrocenyl Phosphorus Thioesters.” Molecules, vol. 25, no. 4, Feb. 2020, p. 939. https://doi.org/10.3390/molecules25040939.