Open Access

Molecules

, volume 25 , issue 7 , pages 1648

Iron Catalysts in Atom Transfer Radical Polymerization

Sajjad Dadashi-Silab ¹

Krzysztof Matyjaszewski ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213, USA |

Publication type: Journal Article

Publication date: 2020-04-03

MDPI

Molecules

scimago Q1

wos Q2

SJR: 0.865

CiteScore: 8.6

Impact factor: 4.6

ISSN: 14203049

DOI: 10.3390/molecules25071648

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PubMed ID: 32260141

Organic Chemistry

Drug Discovery

Physical and Theoretical Chemistry

Pharmaceutical Science

Molecular Medicine

Analytical Chemistry

Chemistry (miscellaneous)

Abstract

Catalysts are essential for mediating a controlled polymerization in atom transfer radical polymerization (ATRP). Copper-based catalysts are widely explored in ATRP and are highly efficient, leading to well-controlled polymerization of a variety of functional monomers. In addition to copper, iron-based complexes offer new opportunities in ATRP catalysis to develop environmentally friendly, less toxic, inexpensive, and abundant catalytic systems. Despite the high efficiency of iron catalysts in controlling polymerization of various monomers including methacrylates and styrene, ATRP of acrylate-based monomers by iron catalysts still remains a challenge. In this paper, we review the fundamentals and recent advances of iron-catalyzed ATRP focusing on development of ligands, catalyst design, and techniques used for iron catalysis in ATRP.

Found

1 citation

Selyutin Artem

PhD in Chemistry

76 publications, 438 citations, 1 review

h-index: 12

Saint Petersburg State University

Research interests

Inorganic Chemistry

1 citation

Melik-Nubarov Nikolay

🥼

DSc in Chemistry

95 publications, 2 649 citations, 3 reviews

h-index: 25

Lomonosov Moscow State University

Research interests

Chemically induced photodynamic teramia

Drug delivery

High molecular weight compounds

Photodynamic Therapy (PDT)

Synthesis of amphiphilic biodegradable copolymers

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Dadashi-Silab S., Matyjaszewski K. Iron Catalysts in Atom Transfer Radical Polymerization // Molecules. 2020. Vol. 25. No. 7. p. 1648.

GOST all authors (up to 50) Copy

Dadashi-Silab S., Matyjaszewski K. Iron Catalysts in Atom Transfer Radical Polymerization // Molecules. 2020. Vol. 25. No. 7. p. 1648.

RIS |

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RIS Copy

TY - JOUR

DO - 10.3390/molecules25071648

UR - https://doi.org/10.3390/molecules25071648

TI - Iron Catalysts in Atom Transfer Radical Polymerization

T2 - Molecules

AU - Dadashi-Silab, Sajjad

AU - Matyjaszewski, Krzysztof

PY - 2020

DA - 2020/04/03

PB - MDPI

SP - 1648

IS - 7

VL - 25

PMID - 32260141

SN - 1420-3049

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2020_Dadashi-Silab,

author = {Sajjad Dadashi-Silab and Krzysztof Matyjaszewski},

title = {Iron Catalysts in Atom Transfer Radical Polymerization},

journal = {Molecules},

year = {2020},

volume = {25},

publisher = {MDPI},

month = {apr},

url = {https://doi.org/10.3390/molecules25071648},

number = {7},

pages = {1648},

doi = {10.3390/molecules25071648}

}

MLA

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MLA Copy

Dadashi-Silab, Sajjad, and Krzysztof Matyjaszewski. “Iron Catalysts in Atom Transfer Radical Polymerization.” Molecules, vol. 25, no. 7, Apr. 2020, p. 1648. https://doi.org/10.3390/molecules25071648.

Publisher

MDPI

Journal

Molecules

scimago Q1

wos Q2

SJR

0.865

CiteScore

8.6

Impact factor

4.6

ISSN

14203049 (Print, Electronic)