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Molecules

, том 25 , издание 17 , страницы 3768

Synthesis of 2-((2-(Benzo[d]oxazol-2-yl)-2H-imidazol -4-yl)amino)-phenols from 2-((5H-1,2,3-Dithiazol -5-ylidene)amino)phenols through Unprecedented Formation of Imidazole Ring from Two Methanimino Groups

Ilia V Baranovsky ¹

Lidia S. Konstantinova ^{1, 2}

Mikhail A Tolmachev ¹

Vadim V Popov ²

Konstantin A Lyssenko ^{3, 4}

Oleg A. Rakitin ^{1, 2}

Скрыть аффилиации авторов Показать аффилиации авторов: 4 аффилиации

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia |

Nanotechnology Education and Research Center, South Ural State University, 454080 Chelyabinsk, Russia |

Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskiye Gory, 1, 119991 Moscow, Russia |

⁴

G. V. Plekhanov Russian University of Economics, 36 Stremyanny Per., 117997 Moscow, Russia |

Тип публикации: Journal Article

Дата публикации: 2020-08-19

MDPI

Molecules

scimago Q1

wos Q2

БС1

SJR: 0.865

CiteScore: 8.6

Impact factor: 4.6

ISSN: 14203049

DOI: 10.3390/molecules25173768

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PubMed ID: 32824981

Organic Chemistry

Drug Discovery

Physical and Theoretical Chemistry

Pharmaceutical Science

Molecular Medicine

Analytical Chemistry

Chemistry (miscellaneous)

Краткое описание

A new synthetic pathway to four substituted imidazoles from readily available 2-((4-aryl(thienyl)-5H-1,2,3-dithiazol-5-ylidene)amino)phenols has been developed. Benzo[d]oxazol-2-yl(aryl(thienyl))methanimines were proved as key intermediates in their synthesis. The formation of an imidazole ring from two methanimine derivatives likely includes the opening of one benzoxazole ring followed by ring closure by intermolecular nucleophilic attack of the N-methanimine atom to a carbon atom of another methanimine.

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Organic and Biomolecular Chemistry	Organic and Biomolecular Chemistry, 1, 50% Organic and Biomolecular Chemistry 1 публикация, 50%
MolBank	MolBank, 1, 50% MolBank 1 публикация, 50%
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Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 50% Royal Society of Chemistry (RSC) 1 публикация, 50%
MDPI	MDPI, 1, 50% MDPI 1 публикация, 50%
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Baranovsky I. V. et al. Synthesis of 2-((2-(Benzo[d]oxazol-2-yl)-2H-imidazol -4-yl)amino)-phenols from 2-((5H-1,2,3-Dithiazol -5-ylidene)amino)phenols through Unprecedented Formation of Imidazole Ring from Two Methanimino Groups // Molecules. 2020. Vol. 25. No. 17. p. 3768.

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Baranovsky I. V., Konstantinova L. S., Tolmachev M. A., Popov V. V., A Lyssenko K., Rakitin O. A. Synthesis of 2-((2-(Benzo[d]oxazol-2-yl)-2H-imidazol -4-yl)amino)-phenols from 2-((5H-1,2,3-Dithiazol -5-ylidene)amino)phenols through Unprecedented Formation of Imidazole Ring from Two Methanimino Groups // Molecules. 2020. Vol. 25. No. 17. p. 3768.

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TY - JOUR

DO - 10.3390/molecules25173768

UR - https://www.mdpi.com/1420-3049/25/17/3768

TI - Synthesis of 2-((2-(Benzo[d]oxazol-2-yl)-2H-imidazol -4-yl)amino)-phenols from 2-((5H-1,2,3-Dithiazol -5-ylidene)amino)phenols through Unprecedented Formation of Imidazole Ring from Two Methanimino Groups

T2 - Molecules

AU - Baranovsky, Ilia V

AU - Konstantinova, Lidia S.

AU - Tolmachev, Mikhail A

AU - Popov, Vadim V

AU - A Lyssenko, Konstantin

AU - Rakitin, Oleg A.

PY - 2020

DA - 2020/08/19

PB - MDPI

SP - 3768

IS - 17

VL - 25

PMID - 32824981

SN - 1420-3049

ER -

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@article{2020_Baranovsky,

author = {Ilia V Baranovsky and Lidia S. Konstantinova and Mikhail A Tolmachev and Vadim V Popov and Konstantin A Lyssenko and Oleg A. Rakitin},

title = {Synthesis of 2-((2-(Benzo[d]oxazol-2-yl)-2H-imidazol -4-yl)amino)-phenols from 2-((5H-1,2,3-Dithiazol -5-ylidene)amino)phenols through Unprecedented Formation of Imidazole Ring from Two Methanimino Groups},

journal = {Molecules},

year = {2020},

volume = {25},

publisher = {MDPI},

month = {aug},

url = {https://www.mdpi.com/1420-3049/25/17/3768},

number = {17},

pages = {3768},

doi = {10.3390/molecules25173768}

}

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Baranovsky, Ilia V., et al. “Synthesis of 2-((2-(Benzo[d]oxazol-2-yl)-2H-imidazol -4-yl)amino)-phenols from 2-((5H-1,2,3-Dithiazol -5-ylidene)amino)phenols through Unprecedented Formation of Imidazole Ring from Two Methanimino Groups.” Molecules, vol. 25, no. 17, Aug. 2020, p. 3768. https://www.mdpi.com/1420-3049/25/17/3768.