Open Access
Mononuclear Copper(I) 3-(2-pyridyl)pyrazole Complexes: The Crucial Role of Phosphine on Photoluminescence
2
Publication type: Journal Article
Publication date: 2021-11-14
PubMed ID:
34833961
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
A series of emissive Cu(I) cationic complexes with 3-(2-pyridyl)-5-phenyl-pyrazole and various phosphines: dppbz (1), Xantphos (2), DPEPhos (3), PPh3 (4), and BINAP (5) were designed and characterized. Complexes obtained exhibit bright yellow-green emission (ca. 520–650 nm) in the solid state with a wide range of QYs (1–78%) and lifetimes (19–119 µs) at 298 K. The photoluminescence efficiency dramatically depends on the phosphine ligand type. The theoretical calculations of buried volumes and excited states explained the emission behavior for 1–5 as well as their lifetimes. The bulky and rigid phosphines promote emission efficiency through the stabilization of singlet and triplet excited states.
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13
Total citations:
13
Citations from 2024:
4
(30%)
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GOST
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Baranova K. F. et al. Mononuclear Copper(I) 3-(2-pyridyl)pyrazole Complexes: The Crucial Role of Phosphine on Photoluminescence // Molecules. 2021. Vol. 26. No. 22. p. 6869.
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Baranova K. F., Titov A. A., Smol’yakov A. F., Chernyadyev A. Y., Filippov O. A., Shubina E. S. Mononuclear Copper(I) 3-(2-pyridyl)pyrazole Complexes: The Crucial Role of Phosphine on Photoluminescence // Molecules. 2021. Vol. 26. No. 22. p. 6869.
Cite this
RIS
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TY - JOUR
DO - 10.3390/molecules26226869
UR - https://doi.org/10.3390/molecules26226869
TI - Mononuclear Copper(I) 3-(2-pyridyl)pyrazole Complexes: The Crucial Role of Phosphine on Photoluminescence
T2 - Molecules
AU - Baranova, Kristina F
AU - Titov, Aleksei A
AU - Smol’yakov, Alexander F.
AU - Chernyadyev, Andrey Yu.
AU - Filippov, Oleg A.
AU - Shubina, Elena S.
PY - 2021
DA - 2021/11/14
PB - MDPI
SP - 6869
IS - 22
VL - 26
PMID - 34833961
SN - 1420-3049
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Baranova,
author = {Kristina F Baranova and Aleksei A Titov and Alexander F. Smol’yakov and Andrey Yu. Chernyadyev and Oleg A. Filippov and Elena S. Shubina},
title = {Mononuclear Copper(I) 3-(2-pyridyl)pyrazole Complexes: The Crucial Role of Phosphine on Photoluminescence},
journal = {Molecules},
year = {2021},
volume = {26},
publisher = {MDPI},
month = {nov},
url = {https://doi.org/10.3390/molecules26226869},
number = {22},
pages = {6869},
doi = {10.3390/molecules26226869}
}
Cite this
MLA
Copy
Baranova, Kristina F., et al. “Mononuclear Copper(I) 3-(2-pyridyl)pyrazole Complexes: The Crucial Role of Phosphine on Photoluminescence.” Molecules, vol. 26, no. 22, Nov. 2021, p. 6869. https://doi.org/10.3390/molecules26226869.