Open Access
Synthesis, Structure, and Electrochemical Properties of 2,3,4,5-Tetraphenyl-1-Monophosphaferrocene Derivatives
Alena R. Lakomkina
1, 2
,
Mikhail Khrizanforov
1, 2
,
R. А. Fayzullin
1
,
Kirill V Kholin
1, 3
,
Ilya A Bezkishko
1
,
Publication type: Journal Article
Publication date: 2023-03-08
PubMed ID:
36985450
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
Heteroleptic 2,3,4,5-tetraphenyl-1-monophosphaferrocene [FeCp(η5-PC4Ph4)] was obtained at a 62% yield through the reaction of lithium 2,3,4,5-tetraphenyl-1-monophosphacyclopentadienide Li(PC4Ph4) (1) with [FeCp(η6-C6H5CH3)][PF6]. The structure of 1-monophosphaferrocene 2 and its W(CO)5-complex 3 were confirmed by multinuclear NMR and single-crystal X-ray diffraction study and further supported by DFT calculations. Cyclic voltammetry demonstrated that [FeCp(η5-PC4Ph4)] 2 has a quasi-reversible oxidation wave. The comparison of the properties of phosphaferrocene 2 with those of W(CO)5-complex 3 shows the possibility of changing the coordination type during oxidation.
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Total citations:
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Citations from 2024:
3
(100%)
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Zagidullin A. A. et al. Synthesis, Structure, and Electrochemical Properties of 2,3,4,5-Tetraphenyl-1-Monophosphaferrocene Derivatives // Molecules. 2023. Vol. 28. No. 6. p. 2481.
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Zagidullin A. A., Lakomkina A. R., Khrizanforov M., Fayzullin R. А., Kholin K. V., Gerasimova T. I., Shekurov R. P., Bezkishko I. A., Miluykov V. Synthesis, Structure, and Electrochemical Properties of 2,3,4,5-Tetraphenyl-1-Monophosphaferrocene Derivatives // Molecules. 2023. Vol. 28. No. 6. p. 2481.
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TY - JOUR
DO - 10.3390/molecules28062481
UR - https://www.mdpi.com/1420-3049/28/6/2481
TI - Synthesis, Structure, and Electrochemical Properties of 2,3,4,5-Tetraphenyl-1-Monophosphaferrocene Derivatives
T2 - Molecules
AU - Zagidullin, Almaz A
AU - Lakomkina, Alena R.
AU - Khrizanforov, Mikhail
AU - Fayzullin, R. А.
AU - Kholin, Kirill V
AU - Gerasimova, Tatiana I.
AU - Shekurov, Ruslan P
AU - Bezkishko, Ilya A
AU - Miluykov, Vasili
PY - 2023
DA - 2023/03/08
PB - MDPI
SP - 2481
IS - 6
VL - 28
PMID - 36985450
SN - 1420-3049
ER -
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BibTex (up to 50 authors)
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@article{2023_Zagidullin,
author = {Almaz A Zagidullin and Alena R. Lakomkina and Mikhail Khrizanforov and R. А. Fayzullin and Kirill V Kholin and Tatiana I. Gerasimova and Ruslan P Shekurov and Ilya A Bezkishko and Vasili Miluykov},
title = {Synthesis, Structure, and Electrochemical Properties of 2,3,4,5-Tetraphenyl-1-Monophosphaferrocene Derivatives},
journal = {Molecules},
year = {2023},
volume = {28},
publisher = {MDPI},
month = {mar},
url = {https://www.mdpi.com/1420-3049/28/6/2481},
number = {6},
pages = {2481},
doi = {10.3390/molecules28062481}
}
Cite this
MLA
Copy
Zagidullin, Almaz A., et al. “Synthesis, Structure, and Electrochemical Properties of 2,3,4,5-Tetraphenyl-1-Monophosphaferrocene Derivatives.” Molecules, vol. 28, no. 6, Mar. 2023, p. 2481. https://www.mdpi.com/1420-3049/28/6/2481.