Open Access
Simmons–Smith Cyclopropanation: A Multifaceted Synthetic Protocol toward the Synthesis of Natural Products and Drugs: A Review
Тип публикации: Journal Article
Дата публикации: 2023-07-26
PubMed ID:
37570621
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Краткое описание
Simmons–Smith cyclopropanation is a widely used reaction in organic synthesis for stereospecific conversion of alkenes into cyclopropane. The utility of this reaction can be realized by the fact that the cyclopropane motif is a privileged synthetic intermediate and a core structural unit of many biologically active natural compounds such as terpenoids, alkaloids, nucleosides, amino acids, fatty acids, polyketides and drugs. The modified form of Simmons–Smith cyclopropanation involves the employment of Et2Zn and CH2I2 (Furukawa reagent) toward the total synthesis of a variety of structurally complex natural products that possess broad range of biological activities including anticancer, antimicrobial and antiviral activities. This review aims to provide an intriguing glimpse of the Furukawa-modified Simmons–Smith cyclopropanation, within the year range of 2005 to 2022.
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ГОСТ
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Munir R. et al. Simmons–Smith Cyclopropanation: A Multifaceted Synthetic Protocol toward the Synthesis of Natural Products and Drugs: A Review // Molecules. 2023. Vol. 28. No. 15. p. 5651.
ГОСТ со всеми авторами (до 50)
Скопировать
Munir R., Zahoor A. F., Javed S., Parveen B., Mansha A., Irfan A., Khan S. G., Irfan A., Kotwica Mojzych K., Mojzych M. Simmons–Smith Cyclopropanation: A Multifaceted Synthetic Protocol toward the Synthesis of Natural Products and Drugs: A Review // Molecules. 2023. Vol. 28. No. 15. p. 5651.
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RIS
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TY - JOUR
DO - 10.3390/molecules28155651
UR - https://doi.org/10.3390/molecules28155651
TI - Simmons–Smith Cyclopropanation: A Multifaceted Synthetic Protocol toward the Synthesis of Natural Products and Drugs: A Review
T2 - Molecules
AU - Munir, Ramsha
AU - Zahoor, Ameer Fawad
AU - Javed, Sadia
AU - Parveen, Bushra
AU - Mansha, Asim
AU - Irfan, Ahmad
AU - Khan, Samreen Gul
AU - Irfan, Ali
AU - Kotwica Mojzych, Katarzyna
AU - Mojzych, Mariusz
PY - 2023
DA - 2023/07/26
PB - MDPI
SP - 5651
IS - 15
VL - 28
PMID - 37570621
SN - 1420-3049
ER -
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BibTex (до 50 авторов)
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@article{2023_Munir,
author = {Ramsha Munir and Ameer Fawad Zahoor and Sadia Javed and Bushra Parveen and Asim Mansha and Ahmad Irfan and Samreen Gul Khan and Ali Irfan and Katarzyna Kotwica Mojzych and Mariusz Mojzych},
title = {Simmons–Smith Cyclopropanation: A Multifaceted Synthetic Protocol toward the Synthesis of Natural Products and Drugs: A Review},
journal = {Molecules},
year = {2023},
volume = {28},
publisher = {MDPI},
month = {jul},
url = {https://doi.org/10.3390/molecules28155651},
number = {15},
pages = {5651},
doi = {10.3390/molecules28155651}
}
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MLA
Скопировать
Munir, Ramsha, et al. “Simmons–Smith Cyclopropanation: A Multifaceted Synthetic Protocol toward the Synthesis of Natural Products and Drugs: A Review.” Molecules, vol. 28, no. 15, Jul. 2023, p. 5651. https://doi.org/10.3390/molecules28155651.
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