Open Access
Polymers, volume 12, issue 12, pages 2925
Resistivity-Temperature Behavior of Intrinsically Conducting Bis(3-methoxysalicylideniminato)nickel Polymer
Publication type: Journal Article
Publication date: 2020-12-06
PubMed ID:
33291328
General Chemistry
Polymers and Plastics
Abstract
Materials with a positive temperature coefficient have many applications, including overcharge and over-temperature protection in lithium-ion (Li-ion) batteries. The thermoresistive properties of an electrically conductive polymer, based on a Ni(salen)-type backbone, known as polyNiMeOSalen, were evaluated by means of in situ resistivity measurements. It was found that the polymer was conductive at temperatures below 220 °C; however, the polymer increased in resistivity by three orders of magnitude upon reaching 250 °C. Thermogravimetric results combined with elemental analyses revealed that the switch from the insulation stage to the conductive stage resulted from thermally dedoping the polymer. Electrochemical studies demonstrated that a polymer retains its electroactivity when it is heated and can be recovered to a conductive state through oxidation via electrochemical doping in an electrolyte solution.
Citations by journals
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Journal of Power Sources
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Journal of Power Sources
1 publication, 25%
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Russian Chemical Reviews
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Russian Chemical Reviews
1 publication, 25%
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Batteries
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Batteries
1 publication, 25%
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Polymer
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Polymer
1 publication, 25%
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1
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Citations by publishers
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2
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Elsevier
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Elsevier
2 publications, 50%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 25%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 25%
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2
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- We do not take into account publications that without a DOI.
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- Statistics recalculated weekly.
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Beletskii E. V. et al. Resistivity-Temperature Behavior of Intrinsically Conducting Bis(3-methoxysalicylideniminato)nickel Polymer // Polymers. 2020. Vol. 12. No. 12. p. 2925.
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Beletskii E. V., Ershov V., Danilov S., Lukyanov D. A., Alekseeva E., Levin O. V. Resistivity-Temperature Behavior of Intrinsically Conducting Bis(3-methoxysalicylideniminato)nickel Polymer // Polymers. 2020. Vol. 12. No. 12. p. 2925.
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TY - JOUR
DO - 10.3390/polym12122925
UR - https://doi.org/10.3390%2Fpolym12122925
TI - Resistivity-Temperature Behavior of Intrinsically Conducting Bis(3-methoxysalicylideniminato)nickel Polymer
T2 - Polymers
AU - Ershov, Valentin
AU - Alekseeva, Elena
AU - Danilov, Stepan
AU - Beletskii, Evgenii V
AU - Lukyanov, Daniil A
AU - Levin, Oleg V.
PY - 2020
DA - 2020/12/06 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 2925
IS - 12
VL - 12
PMID - 33291328
SN - 2073-4360
ER -
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@article{2020_Beletskii,
author = {Valentin Ershov and Elena Alekseeva and Stepan Danilov and Evgenii V Beletskii and Daniil A Lukyanov and Oleg V. Levin},
title = {Resistivity-Temperature Behavior of Intrinsically Conducting Bis(3-methoxysalicylideniminato)nickel Polymer},
journal = {Polymers},
year = {2020},
volume = {12},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {dec},
url = {https://doi.org/10.3390%2Fpolym12122925},
number = {12},
pages = {2925},
doi = {10.3390/polym12122925}
}
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Beletskii, Evgenii V., et al. “Resistivity-Temperature Behavior of Intrinsically Conducting Bis(3-methoxysalicylideniminato)nickel Polymer.” Polymers, vol. 12, no. 12, Dec. 2020, p. 2925. https://doi.org/10.3390%2Fpolym12122925.