Open Access
Co3O4 as p-Type Material for CO Sensing in Humid Air
Svetlana Vladimirova
1
,
Marina Rumyantseva
1
,
Alexander Gaskov
1
,
Natalia Mordvinova
1, 2
,
Oleg Lebedev
2
,
Mikhail Martyshov
3
,
Pavel Forsh
3, 4
2
Laboratoire CRISMAT, ENSICAEN-CNRS UMR6508, Caen 14050, France
|
Publication type: Journal Article
Publication date: 2017-09-27
scimago Q1
wos Q2
SJR: 0.764
CiteScore: 8.2
Impact factor: 3.5
ISSN: 14243210, 14248220
PubMed ID:
28953228
Biochemistry
Analytical Chemistry
Atomic and Molecular Physics, and Optics
Electrical and Electronic Engineering
Instrumentation
Abstract
Nanocrystalline cobalt oxide Co3O4 has been prepared by precipitation and subsequent thermal decomposition of a carbonate precursor, and has been characterized in detail using XRD, transmission electron microscopy, and FTIR spectroscopy. The sensory characteristics of the material towards carbon monoxide in the concentration range 6.7–20 ppm have been examined in both dry and humid air. A sensor signal is achieved in dry air at sufficiently low temperatures T = 80–120 °C, but the increase in relative humidity results in the disappearance of sensor signal in this temperature range. At temperatures above 200 °C the inversion of the sensor signal in dry air was observed. In the temperature interval 180–200 °C the sensor signal toward CO is nearly the same at 0, 20 and 60% r.h. The obtained results are discussed in relation with the specific features of the adsorption of CO, oxygen, and water molecules on the surface of Co3O4. The independence of the sensor signal from the air humidity combined with a sufficiently short response time at a moderate operating temperature makes Co3O4 a very promising material for CO detection in conditions of variable humidity.
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Total citations:
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GOST
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Vladimirova S. et al. Co3O4 as p-Type Material for CO Sensing in Humid Air // Sensors. 2017. Vol. 17. No. 10. p. 2216.
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Vladimirova S., Krivetskiy V., Rumyantseva M., Gaskov A., Mordvinova N., Lebedev O., Martyshov M., Forsh P. Co3O4 as p-Type Material for CO Sensing in Humid Air // Sensors. 2017. Vol. 17. No. 10. p. 2216.
Cite this
RIS
Copy
TY - JOUR
DO - 10.3390/s17102216
UR - https://doi.org/10.3390/s17102216
TI - Co3O4 as p-Type Material for CO Sensing in Humid Air
T2 - Sensors
AU - Vladimirova, Svetlana
AU - Krivetskiy, Valeriy
AU - Rumyantseva, Marina
AU - Gaskov, Alexander
AU - Mordvinova, Natalia
AU - Lebedev, Oleg
AU - Martyshov, Mikhail
AU - Forsh, Pavel
PY - 2017
DA - 2017/09/27
PB - MDPI
SP - 2216
IS - 10
VL - 17
PMID - 28953228
SN - 1424-3210
SN - 1424-8220
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Vladimirova,
author = {Svetlana Vladimirova and Valeriy Krivetskiy and Marina Rumyantseva and Alexander Gaskov and Natalia Mordvinova and Oleg Lebedev and Mikhail Martyshov and Pavel Forsh},
title = {Co3O4 as p-Type Material for CO Sensing in Humid Air},
journal = {Sensors},
year = {2017},
volume = {17},
publisher = {MDPI},
month = {sep},
url = {https://doi.org/10.3390/s17102216},
number = {10},
pages = {2216},
doi = {10.3390/s17102216}
}
Cite this
MLA
Copy
Vladimirova, Svetlana, et al. “Co3O4 as p-Type Material for CO Sensing in Humid Air.” Sensors, vol. 17, no. 10, Sep. 2017, p. 2216. https://doi.org/10.3390/s17102216.
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