Open Access

Sensors, volume 22, issue 24, pages 9800

Atmospheric Pressure Solvothermal Synthesis of Nanoscale SnO2 and Its Application in Microextrusion Printing of a Thick-Film Chemosensor Material for Effective Ethanol Detection

Fisenko Nikita A ^{1, 2}

Solomatov Ivan A ³

Simonenko Nikolay P. ¹

Mokrushin Artem S. ¹

Gorobtsov Philipp Yu. ¹

Simonenko Tatiana L. ¹

Volkov Ivan A. ⁴

Simonenko Elizaveta P. ¹

Kuznetsov Nikolay T. ¹

Hide authors affiliations Show authors affiliations: 4 affiliations

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 31 Leninsky Pr., Moscow 119991, Russia |

Higher Chemical College of the Russian Academy of Sciences, D. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya sq., Moscow 125047, Russia |

Basic Department of Inorganic Chemistry and Materials Science, National Research University “Higher School of Economics”, 20 Myasnsitskaya str., Moscow 101978, Russia |

⁴

Moscow Institute of Physics and Technology, National Research University, 9 Institutskiy per., Dolgoprudny 141701, Russia |

Publication type: Journal Article

Publication date: 2022-12-14

Multidisciplinary Digital Publishing Institute (MDPI)

Journal: Sensors

Quartile SCImago

Quartile WOS

Impact factor: 3.9

ISSN: 14243210, 14248220

DOI: 10.3390/s22249800

Copy DOI

Biochemistry

Analytical Chemistry

Atomic and Molecular Physics, and Optics

Electrical and Electronic Engineering

Instrumentation

Abstract

The atmospheric pressure solvothermal (APS) synthesis of nanocrystalline SnO2 (average size of coherent scattering regions (CSR)—7.5 ± 0.6 nm) using tin acetylacetonate as a precursor was studied. The resulting nanopowder was used as a functional ink component in microextrusion printing of a tin dioxide thick film on the surface of a Pt/Al2O3/Pt chip. Synchronous thermal analysis shows that the resulting semiproduct is transformed completely into tin dioxide nanopowder at 400 °C within 1 h. The SnO2 powder and the resulting film were shown to have a cassiterite-type structure according to X-ray diffraction analysis, and IR spectroscopy was used to establish the set of functional groups in the material composition. The microstructural features of the tin dioxide powder were analyzed using scanning (SEM) and transmission (TEM) electron microscopy: the average size of the oxide powder particles was 8.2 ± 0.7 nm. Various atomic force microscopy (AFM) techniques were employed to investigate the topography of the oxide film and to build maps of surface capacitance and potential distribution. The temperature dependence of the electrical conductivity of the printed SnO2 film was studied using impedance spectroscopy. The chemosensory properties of the formed material when detecting H2, CO, NH3, C6H6, C3H6O and C2H5OH, including at varying humidity, were also examined. It was demonstrated that the obtained SnO2 film has an increased sensitivity (the sensory response value was 1.4–63.5) and selectivity for detection of 4–100 ppm C2H5OH at an operating temperature of 200 °C.

By date By citations

Citations by journals

	1 2
Chemosensors	Chemosensors, 2, 66.67% Chemosensors 2 publications, 66.67%
Applied Sciences (Switzerland)	Applied Sciences (Switzerland), 1, 33.33% Applied Sciences (Switzerland) 1 publication, 33.33%
	1 2

Citations by publishers

	1 2 3
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 3, 100% Multidisciplinary Digital Publishing Institute (MDPI) 3 publications, 100%
	1 2 3

We do not take into account publications that without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2023],"ids":[0],"codes":[0],"imageUrls":[""],"datasets":[{"label":"Citations number","data":[3],"backgroundColor":["#3B82F6"],"percentage":["100"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Chemosensors","Applied Sciences (Switzerland)"],"ids":[2627,16650],"codes":[0,0],"imageUrls":["\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp"],"datasets":[{"label":"","data":[2,1],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":[66.67,33.33],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Multidisciplinary Digital Publishing Institute (MDPI)"],"ids":[202],"codes":[0],"imageUrls":["\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp"],"datasets":[{"label":"","data":[3],"backgroundColor":["#3B82F6"],"percentage":[100],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Publication PDF

Metrics

Cite this

GOST |

Cite this

GOST Copy

Fisenko N. A. et al. Atmospheric Pressure Solvothermal Synthesis of Nanoscale SnO2 and Its Application in Microextrusion Printing of a Thick-Film Chemosensor Material for Effective Ethanol Detection // Sensors. 2022. Vol. 22. No. 24. p. 9800.

GOST all authors (up to 50) Copy

Fisenko N. A., Solomatov I. A., Simonenko N. P., Mokrushin A. S., Gorobtsov P. Y., Simonenko T. L., Volkov I. A., Simonenko E. P., Kuznetsov N. T. Atmospheric Pressure Solvothermal Synthesis of Nanoscale SnO2 and Its Application in Microextrusion Printing of a Thick-Film Chemosensor Material for Effective Ethanol Detection // Sensors. 2022. Vol. 22. No. 24. p. 9800.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.3390/s22249800

UR - https://doi.org/10.3390%2Fs22249800

TI - Atmospheric Pressure Solvothermal Synthesis of Nanoscale SnO2 and Its Application in Microextrusion Printing of a Thick-Film Chemosensor Material for Effective Ethanol Detection

T2 - Sensors

AU - Fisenko, Nikita A

AU - Solomatov, Ivan A

AU - Simonenko, Nikolay P.

AU - Mokrushin, Artem S.

AU - Gorobtsov, Philipp Yu.

AU - Simonenko, Tatiana L.

AU - Volkov, Ivan A.

AU - Simonenko, Elizaveta P.

AU - Kuznetsov, Nikolay T.

PY - 2022

DA - 2022/12/14 00:00:00

PB - Multidisciplinary Digital Publishing Institute (MDPI)

SP - 9800

IS - 24

VL - 22

SN - 1424-3210

SN - 1424-8220

ER -

BibTex |

Cite this

BibTex Copy

@article{2022_Fisenko,

author = {Nikita A Fisenko and Ivan A Solomatov and Nikolay P. Simonenko and Artem S. Mokrushin and Philipp Yu. Gorobtsov and Tatiana L. Simonenko and Ivan A. Volkov and Elizaveta P. Simonenko and Nikolay T. Kuznetsov},

title = {Atmospheric Pressure Solvothermal Synthesis of Nanoscale SnO2 and Its Application in Microextrusion Printing of a Thick-Film Chemosensor Material for Effective Ethanol Detection},

journal = {Sensors},

year = {2022},

volume = {22},

publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},

month = {dec},

url = {https://doi.org/10.3390%2Fs22249800},

number = {24},

pages = {9800},

doi = {10.3390/s22249800}

}

MLA

Cite this

MLA Copy

Fisenko, Nikita A., et al. “Atmospheric Pressure Solvothermal Synthesis of Nanoscale SnO2 and Its Application in Microextrusion Printing of a Thick-Film Chemosensor Material for Effective Ethanol Detection.” Sensors, vol. 22, no. 24, Dec. 2022, p. 9800. https://doi.org/10.3390%2Fs22249800.

Found error?

Publisher

Multidisciplinary Digital Publishing Institute (MDPI)

Journal

Sensors

Quartile SCImago

Quartile WOS

Impact factor

3.9

ISSN

14243210 (Print)
14248220 (Electronic)

Profiles

News

Чернила на основе оксида олова стали основой детекторов спирта