Synthesis of 1,4-Bis(n-propoxy)pillar[7]arene and Its Host-guest Chemistry
Publication type: Journal Article
Publication date: 2012-10-10
scimago Q3
wos Q3
SJR: 0.329
CiteScore: 3.2
Impact factor: 1.6
ISSN: 05677351, 02567660
General Chemistry
Abstract
我们以1,4-二正丙氧基-2,5-双甲氧甲基苯为原料用对甲苯磺酸为催化剂在二氯甲烷中制备了1,4-双正丙氧基柱[5]芳烃,1,4-双正丙氧基柱[6]芳烃和1,4-双正丙氧基柱[7]芳烃.我们用氢谱、碳谱和质谱对它们进行了表征.它们有不同的氢谱却有相似的碳谱.对比它们的空腔尺寸,柱[5]的内径大约是4.6,与葫芦脲[6]及α-环糊精类似.柱[6]的内径大约是6.7,与葫芦脲[7]及β-环糊精类似.柱[7]的内径大约是8.7,与葫芦脲[8]及γ-环糊精类似.我们用正辛基三乙基六氟磷酸铵盐作为模型客体研究了它们之间的主客体络合.柱[5]与之有微弱的络合,柱[6]显示了良好的络合,而柱[7]与之没有络合.
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Total citations:
41
Citations from 2024:
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(4%)
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GOST
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Han C. et al. Synthesis of 1,4-Bis(n-propoxy)pillar[7]arene and Its Host-guest Chemistry // Acta Chimica Sinica. 2012. Vol. 70. No. 17. p. 1775.
GOST all authors (up to 50)
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Han C., Zhang Z., Chi X., Zhang M., Yu G., Huang F. Synthesis of 1,4-Bis(n-propoxy)pillar[7]arene and Its Host-guest Chemistry // Acta Chimica Sinica. 2012. Vol. 70. No. 17. p. 1775.
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RIS
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TY - JOUR
DO - 10.6023/a12060296
UR - https://doi.org/10.6023/a12060296
TI - Synthesis of 1,4-Bis(n-propoxy)pillar[7]arene and Its Host-guest Chemistry
T2 - Acta Chimica Sinica
AU - Han, Chengyou
AU - Zhang, Zibin
AU - Chi, Xiaodong
AU - Zhang, Mingming
AU - Yu, Guocan
AU - Huang, Feihe
PY - 2012
DA - 2012/10/10
PB - Shanghai Institute of Organic Chemistry
SP - 1775
IS - 17
VL - 70
SN - 0567-7351
SN - 0256-7660
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Han,
author = {Chengyou Han and Zibin Zhang and Xiaodong Chi and Mingming Zhang and Guocan Yu and Feihe Huang},
title = {Synthesis of 1,4-Bis(n-propoxy)pillar[7]arene and Its Host-guest Chemistry},
journal = {Acta Chimica Sinica},
year = {2012},
volume = {70},
publisher = {Shanghai Institute of Organic Chemistry},
month = {oct},
url = {https://doi.org/10.6023/a12060296},
number = {17},
pages = {1775},
doi = {10.6023/a12060296}
}
Cite this
MLA
Copy
Han, Chengyou, et al. “Synthesis of 1,4-Bis(n-propoxy)pillar[7]arene and Its Host-guest Chemistry.” Acta Chimica Sinica, vol. 70, no. 17, Oct. 2012, p. 1775. https://doi.org/10.6023/a12060296.