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volume 7 issue 3 pages 256-261

Synthesis of the first azomethine derivatives of PdII coproporphyrins I and II

Alexander N Volov
Dina R. Erzina
Gelii V. Ponomarev
Oscar I. Koifman
Publication typeJournal Article
Publication date2014-12-19
scimago Q4
wos Q3
SJR0.193
CiteScore1.5
Impact factor1.2
ISSN19989539, 27131092
Organic Chemistry
Analytical Chemistry
Abstract
The effective synthesis of Pd(II) monofunctional azomethine derivatives of coproporphyrin isomers I and II is reported. The proposed method is based on the interaction of a “phosphorus complex”, generated in situ by Vilsmeier-Haack reaction, with various amines. The reaction with palladium complex of coproporphyrin II gave Schiff bases as a mixture of two structural isomers in 4:1 ratio. The structure of the obtained compounds was determined using 1H, 13C, 1H-1H NOESY and UV-vis spectroscopy and mass spectrometry data.
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Volov A. N. et al. Synthesis of the first azomethine derivatives of PdII coproporphyrins I and II // Macroheterocycles. 2014. Vol. 7. No. 3. pp. 256-261.
GOST all authors (up to 50) Copy
Volov A. N., Mikhel I. S., Zamilatskov I. A., Erzina D. R., Ponomarev G. V., Koifman O. I., Tsivadze A. Y. Synthesis of the first azomethine derivatives of PdII coproporphyrins I and II // Macroheterocycles. 2014. Vol. 7. No. 3. pp. 256-261.
RIS |
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RIS Copy
TY - JOUR
DO - 10.6060/mhc140274z
UR - http://macroheterocycles.isuct.ru/en/mhc140274z
TI - Synthesis of the first azomethine derivatives of PdII coproporphyrins I and II
T2 - Macroheterocycles
AU - Volov, Alexander N
AU - Mikhel, Igor S
AU - Zamilatskov, Ilya A
AU - Erzina, Dina R.
AU - Ponomarev, Gelii V.
AU - Koifman, Oscar I.
AU - Tsivadze, Aslan Yu.
PY - 2014
DA - 2014/12/19
PB - Ivanovo State University of Chemistry and Technology
SP - 256-261
IS - 3
VL - 7
SN - 1998-9539
SN - 2713-1092
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2014_Volov,
author = {Alexander N Volov and Igor S Mikhel and Ilya A Zamilatskov and Dina R. Erzina and Gelii V. Ponomarev and Oscar I. Koifman and Aslan Yu. Tsivadze},
title = {Synthesis of the first azomethine derivatives of PdII coproporphyrins I and II},
journal = {Macroheterocycles},
year = {2014},
volume = {7},
publisher = {Ivanovo State University of Chemistry and Technology},
month = {dec},
url = {http://macroheterocycles.isuct.ru/en/mhc140274z},
number = {3},
pages = {256--261},
doi = {10.6060/mhc140274z}
}
MLA
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MLA Copy
Volov, Alexander N., et al. “Synthesis of the first azomethine derivatives of PdII coproporphyrins I and II.” Macroheterocycles, vol. 7, no. 3, Dec. 2014, pp. 256-261. http://macroheterocycles.isuct.ru/en/mhc140274z.