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(24-Crown-8)-linked dimeric phthalocyanines and their metal complexes
Publication type: Journal Article
Publication date: 2014-07-11
scimago Q4
wos Q3
SJR: 0.193
CiteScore: 1.5
Impact factor: 1.2
ISSN: 19989539, 27131092
Organic Chemistry
Analytical Chemistry
Abstract
A convenient synthetic approach towards alkyloxy substituted (24-crown-8)-linked dimeric phthalocyanines is developed. The influence of the alteration of the reaction conditions and the origin of the precursors onto the yield of the target compounds is revealed. The Mg-templated statistical condensation of the mixture of phthalonitriles is found to be the most efficient and versatile pathway. The developed demetallation procedure of obtained Mg-phthalocyanines allows to prepare metal-free (24-crown-8)-linked dimeric phthalocyanines, which are versatile precursors for preparation of other metal complexes. The preliminary AM1 semi-empirical calculations have demonstrated that the dimeric linked phthalocyanine metal complexes may become convenient receptors for recognition of ditopic guests.
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Birin K. P. et al. (24-Crown-8)-linked dimeric phthalocyanines and their metal complexes // Macroheterocycles. 2014. Vol. 7. No. 2. pp. 153-161.
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Birin K. P., Chugunov V. N., Krapivenko A. A., Gorbunova Y. G., Tsivadze A. Y. (24-Crown-8)-linked dimeric phthalocyanines and their metal complexes // Macroheterocycles. 2014. Vol. 7. No. 2. pp. 153-161.
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TY - JOUR
DO - 10.6060/mhc140508b
UR - http://macroheterocycles.isuct.ru/en/annot/t07n02/153
TI - (24-Crown-8)-linked dimeric phthalocyanines and their metal complexes
T2 - Macroheterocycles
AU - Birin, Kirill P.
AU - Chugunov, Victor N
AU - Krapivenko, Anna A
AU - Gorbunova, Yulia G.
AU - Tsivadze, Aslan Yu.
PY - 2014
DA - 2014/07/11
PB - Ivanovo State University of Chemistry and Technology
SP - 153-161
IS - 2
VL - 7
SN - 1998-9539
SN - 2713-1092
ER -
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@article{2014_Birin,
author = {Kirill P. Birin and Victor N Chugunov and Anna A Krapivenko and Yulia G. Gorbunova and Aslan Yu. Tsivadze},
title = {(24-Crown-8)-linked dimeric phthalocyanines and their metal complexes},
journal = {Macroheterocycles},
year = {2014},
volume = {7},
publisher = {Ivanovo State University of Chemistry and Technology},
month = {jul},
url = {http://macroheterocycles.isuct.ru/en/annot/t07n02/153},
number = {2},
pages = {153--161},
doi = {10.6060/mhc140508b}
}
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MLA
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Birin, Kirill P., et al. “(24-Crown-8)-linked dimeric phthalocyanines and their metal complexes.” Macroheterocycles, vol. 7, no. 2, Jul. 2014, pp. 153-161. http://macroheterocycles.isuct.ru/en/annot/t07n02/153.