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The role of oxygen in electrochemical reduction of double-decker phthalocyaninates of lanthanides
Publication type: Journal Article
Publication date: 2015-10-28
scimago Q4
wos Q3
SJR: 0.193
CiteScore: 1.5
Impact factor: 1.2
ISSN: 19989539, 27131092
Organic Chemistry
Analytical Chemistry
Abstract
The influence of air oxygen on the processes of electrochemical reduction of double-decker 15-crown-5 substituted lanthanide phthalocyaninates in solutions and Langmuir-Blodgett films on electrode surfaces was revealed. The multistage nature of the process, associated with formation of the intermediate oxygen-containing complexes of the studied compounds in the presence of atmospheric oxygen, was confirmed by cyclic voltammetry and spectroelectrochemical measurements. It was shown that spectra of the electrochemically reduced forms of complexes coincide with ones obtained via chemical reduction only upon application of extremely negative potentials or in the absence of air oxygen in electrolyte.
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Selektor S. L. et al. The role of oxygen in electrochemical reduction of double-decker phthalocyaninates of lanthanides // Macroheterocycles. 2015. Vol. 8. No. 2. pp. 135-142.
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Selektor S. L., Shokurov A. V., Revina A., Arslanov V., Gorbunova Y. G., Tsivadze A. Y. The role of oxygen in electrochemical reduction of double-decker phthalocyaninates of lanthanides // Macroheterocycles. 2015. Vol. 8. No. 2. pp. 135-142.
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RIS
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TY - JOUR
DO - 10.6060/mhc150765s
UR - https://macroheterocycles.isuct.ru/en/mhc150765s
TI - The role of oxygen in electrochemical reduction of double-decker phthalocyaninates of lanthanides
T2 - Macroheterocycles
AU - Selektor, S L
AU - Shokurov, A V
AU - Revina, A.A
AU - Arslanov, V.V
AU - Gorbunova, Yu. G.
AU - Tsivadze, A. Yu.
PY - 2015
DA - 2015/10/28
PB - Ivanovo State University of Chemistry and Technology
SP - 135-142
IS - 2
VL - 8
SN - 1998-9539
SN - 2713-1092
ER -
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BibTex (up to 50 authors)
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@article{2015_Selektor,
author = {S L Selektor and A V Shokurov and A.A Revina and V.V Arslanov and Yu. G. Gorbunova and A. Yu. Tsivadze},
title = {The role of oxygen in electrochemical reduction of double-decker phthalocyaninates of lanthanides},
journal = {Macroheterocycles},
year = {2015},
volume = {8},
publisher = {Ivanovo State University of Chemistry and Technology},
month = {oct},
url = {https://macroheterocycles.isuct.ru/en/mhc150765s},
number = {2},
pages = {135--142},
doi = {10.6060/mhc150765s}
}
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MLA
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Selektor, S. L., et al. “The role of oxygen in electrochemical reduction of double-decker phthalocyaninates of lanthanides.” Macroheterocycles, vol. 8, no. 2, Oct. 2015, pp. 135-142. https://macroheterocycles.isuct.ru/en/mhc150765s.