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Revisiting the one-step synthesis of heteroleptic lanthanide(III) (porphyrinato)(phthalocyaninates): Opportunities and limitations
Publication type: Journal Article
Publication date: 2017-01-01
scimago Q4
wos Q3
SJR: 0.193
CiteScore: 1.5
Impact factor: 1.2
ISSN: 19989539, 27131092
Organic Chemistry
Analytical Chemistry
Abstract
The influence of the porphyrin and phthalocyanine ligand nature onto the yield and selectivity in the one-step synthesis of heteroleptic triple-decker early lanthanide (porphyrinato)(phthalocyaninates) is investigated with 6 porphyrins, 4 phthalocyanines and 2 lanthanides as examples. It is found that the presence of electron-donating substituents in the phthalocyanine macrocycle allows efficient one-step formation of symmetrical triple-decker complexes of [Por]Ln[Pc]Ln[Por] type. In contrast, in the case of unsubstituted phthalocyanine only formation of double-decker complex was observed. The method was found to be limited for the preparation of complexes, containing porphyrins with unsubstituted meso-positions because of their degradation upon reaction course as well as porphyrins with bulky meso-substituents as a result of steric hindrances.
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Birin K. P. et al. Revisiting the one-step synthesis of heteroleptic lanthanide(III) (porphyrinato)(phthalocyaninates): Opportunities and limitations // Macroheterocycles. 2017. Vol. 10. No. 4-5. pp. 514-515.
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Birin K. P., Poddubnaya A. I., Gorbunova Y. G., Tsivadze A. Y. Revisiting the one-step synthesis of heteroleptic lanthanide(III) (porphyrinato)(phthalocyaninates): Opportunities and limitations // Macroheterocycles. 2017. Vol. 10. No. 4-5. pp. 514-515.
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TY - JOUR
DO - 10.6060/mhc171258b
UR - https://macroheterocycles.isuct.ru/en/mhc171258b
TI - Revisiting the one-step synthesis of heteroleptic lanthanide(III) (porphyrinato)(phthalocyaninates): Opportunities and limitations
T2 - Macroheterocycles
AU - Birin, Kirill P.
AU - Poddubnaya, Anna I
AU - Gorbunova, Yulia G.
AU - Tsivadze, Aslan Yu.
PY - 2017
DA - 2017/01/01
PB - Ivanovo State University of Chemistry and Technology
SP - 514-515
IS - 4-5
VL - 10
SN - 1998-9539
SN - 2713-1092
ER -
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@article{2017_Birin,
author = {Kirill P. Birin and Anna I Poddubnaya and Yulia G. Gorbunova and Aslan Yu. Tsivadze},
title = {Revisiting the one-step synthesis of heteroleptic lanthanide(III) (porphyrinato)(phthalocyaninates): Opportunities and limitations},
journal = {Macroheterocycles},
year = {2017},
volume = {10},
publisher = {Ivanovo State University of Chemistry and Technology},
month = {jan},
url = {https://macroheterocycles.isuct.ru/en/mhc171258b},
number = {4-5},
pages = {514--515},
doi = {10.6060/mhc171258b}
}
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Birin, Kirill P., et al. “Revisiting the one-step synthesis of heteroleptic lanthanide(III) (porphyrinato)(phthalocyaninates): Opportunities and limitations.” Macroheterocycles, vol. 10, no. 4-5, Jan. 2017, pp. 514-515. https://macroheterocycles.isuct.ru/en/mhc171258b.