Pure and Applied Chemistry, volume 92, issue 7, pages 1093-1110

Some aspects of the formation and structural features of low nuclearity heterometallic carboxylates

Publication typeJournal Article
Publication date2020-04-17
Quartile SCImago
Q2
Quartile WOS
Q3
Impact factor1.8
ISSN00334545
General Chemistry
General Chemical Engineering
Abstract

Heterometallic carboxylate complexes are of paramount interest in pure and applied coordination chemistry. Despite that plurality of such type compounds have been published to date, synthetic aspects of their chemistry often remain in the shadow of intriguing physical properties manifesting by these species. Present review summarizes reliable data on direct synthesis of low nuclearity molecular compounds as well as coordination polymers on their base with carboxylate-bridged {M2Mg} (M = Co2+, Ni2+, Cd2+), {M2Li2} (M = Co2+, Ni2+, Zn2+, VO2+), {M2Ln2} and {M2Ln} (M = Cu2+, Zn2+, Co2+) metal cores. Structural features and stabilization factors are considered and principal outcomes are confirmed by quantum-chemical calculations. Particular attention is paid to consideration of ligand-exchange reactions that allow controllable modification of heterometallic metal core under mild conditions giving diverse molecular complexes with modified ligand environment or Metal-Organic Frameworks with permanent porosity.

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GOST Copy
Sidorov A. et al. Some aspects of the formation and structural features of low nuclearity heterometallic carboxylates // Pure and Applied Chemistry. 2020. Vol. 92. No. 7. pp. 1093-1110.
GOST all authors (up to 50) Copy
Sidorov A., Gogoleva N. V., Bazhina E. S., Nikolaevskii S. A., Shmelev M. A., Zorina-Tikhonova E. N., Starikov A. G., Kiskin M. A., Eremenko I. L. Some aspects of the formation and structural features of low nuclearity heterometallic carboxylates // Pure and Applied Chemistry. 2020. Vol. 92. No. 7. pp. 1093-1110.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1515/pac-2019-1212
UR - https://doi.org/10.1515%2Fpac-2019-1212
TI - Some aspects of the formation and structural features of low nuclearity heterometallic carboxylates
T2 - Pure and Applied Chemistry
AU - Sidorov, A.V
AU - Gogoleva, Natalia V
AU - Bazhina, Evgeniya S
AU - Nikolaevskii, Stanislav Alexandrovich
AU - Shmelev, M. A.
AU - Zorina-Tikhonova, Ekaterina N.
AU - Starikov, A. G.
AU - Kiskin, Mikhail A.
AU - Eremenko, Igor L.
PY - 2020
DA - 2020/04/17 00:00:00
PB - Walter de Gruyter
SP - 1093-1110
IS - 7
VL - 92
SN - 0033-4545
ER -
BibTex |
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BibTex Copy
@article{2020_Sidorov,
author = {A.V Sidorov and Natalia V Gogoleva and Evgeniya S Bazhina and Stanislav Alexandrovich Nikolaevskii and M. A. Shmelev and Ekaterina N. Zorina-Tikhonova and A. G. Starikov and Mikhail A. Kiskin and Igor L. Eremenko},
title = {Some aspects of the formation and structural features of low nuclearity heterometallic carboxylates},
journal = {Pure and Applied Chemistry},
year = {2020},
volume = {92},
publisher = {Walter de Gruyter},
month = {apr},
url = {https://doi.org/10.1515%2Fpac-2019-1212},
number = {7},
pages = {1093--1110},
doi = {10.1515/pac-2019-1212}
}
MLA
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MLA Copy
Sidorov, A.V, et al. “Some aspects of the formation and structural features of low nuclearity heterometallic carboxylates.” Pure and Applied Chemistry, vol. 92, no. 7, Apr. 2020, pp. 1093-1110. https://doi.org/10.1515%2Fpac-2019-1212.
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