Journal of Fluorine Chemistry, volume 244, pages 109742

Hydrophobization of organic resorcinol-formaldehyde aerogels by fluoroacylation

Kopitsa G. P. 2, 3
Malkova Alena N 1
Baranchikov Alexander E.
Bespalov Alexander S 4
Publication typeJournal Article
Publication date2021-04-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor1.9
ISSN00221139
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Environmental Chemistry
Abstract
Abstract Resorcinol-formaldehyde aerogels (RF AGs) of two density values (0.15 and 0.64 g/cm3) were acylated by an excess of perfluoroalkane carboxylic anhydrides (RFCO)2O (R = CF3, C8F17). After acylation by perfluorononanoic acid anhydride the resulting fluorinated aerogels retained high specific surface area (270−345 m2/g) and acquired high hydrophobicity – water drop contact angle value reached 145°. Besides, these samples demonstrated low water vapour and liquid water absorption.

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Lermontov S. A. et al. Hydrophobization of organic resorcinol-formaldehyde aerogels by fluoroacylation // Journal of Fluorine Chemistry. 2021. Vol. 244. p. 109742.
GOST all authors (up to 50) Copy
Lermontov S. A., Malkova A. N., Sipyagina N. A., Baranchikov A. E., Kopitsa G. P., Bespalov A. S., Baranchikov A. E. Hydrophobization of organic resorcinol-formaldehyde aerogels by fluoroacylation // Journal of Fluorine Chemistry. 2021. Vol. 244. p. 109742.
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RIS Copy
TY - JOUR
DO - 10.1016/j.jfluchem.2021.109742
UR - https://doi.org/10.1016%2Fj.jfluchem.2021.109742
TI - Hydrophobization of organic resorcinol-formaldehyde aerogels by fluoroacylation
T2 - Journal of Fluorine Chemistry
AU - Lermontov, Sergey A
AU - Malkova, Alena N
AU - Sipyagina, Nataliya A
AU - Baranchikov, Alexander E.
AU - Kopitsa, G. P.
AU - Bespalov, Alexander S
AU - Baranchikov, Alexander E
PY - 2021
DA - 2021/04/01 00:00:00
PB - Elsevier
SP - 109742
VL - 244
SN - 0022-1139
ER -
BibTex
Cite this
BibTex Copy
@article{2021_Lermontov,
author = {Sergey A Lermontov and Alena N Malkova and Nataliya A Sipyagina and Alexander E. Baranchikov and G. P. Kopitsa and Alexander S Bespalov and Alexander E Baranchikov},
title = {Hydrophobization of organic resorcinol-formaldehyde aerogels by fluoroacylation},
journal = {Journal of Fluorine Chemistry},
year = {2021},
volume = {244},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016%2Fj.jfluchem.2021.109742},
pages = {109742},
doi = {10.1016/j.jfluchem.2021.109742}
}
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