Inorganic Chemistry, volume 60, issue 20, pages 15509-15518
Ion-Driven Self-Assembly of Lanthanide Bis-phthalocyaninates into Conductive Quasi-MOF Nanowires: An Approach toward Easily Recyclable Organic Electronics
Tameev Alexey
1
,
Ежов А. А.
3
,
Publication type: Journal Article
Publication date: 2021-10-06
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Controlled self-assembly and rapid disintegration of supramolecular nanowires is potentially useful for ecology-friendly organic electronics. Herein, a novel method exploiting the binding between crown-substituted double-decker lanthanide phthalocyaninates (ML2, M = Lu, Ce, Tb) and K+ ions is applied for the one-step fabrication of macroscopically long conductive one-dimensional quasi-metal-organic frameworks. Their properties are controlled by the size of the lanthanide ion guiding the assembly through either intra- or intermolecular interactions. A LuL2 linker with a small interdeck distance yields fully conjugated intermolecular-bonded K+-LuL2 nanowires with a thickness of 10-50 nm, a length of up to 50 μm, and a conductivity of up to 11.4 S cm-1, the highest among them being reported for phthalocyanine assemblies. The large size of CeL2 and TbL2 leads to the formation of mixed intra- and intermolecular K+-ML2 phases with poor electric properties. A field-assisted method is developed to deposit aligned conductive K+-LuL2 assemblies on solids. The solid-supported nanowires can be disintegrated into starting components in a good aprotic solvent for further recycling.
Citations by journals
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2
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Journal of Porphyrins and Phthalocyanines
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Journal of Porphyrins and Phthalocyanines
2 publications, 40%
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ACS Omega
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ACS Omega
1 publication, 20%
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Colloid Journal
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Colloid Journal
1 publication, 20%
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Chemical Society Reviews
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Chemical Society Reviews
1 publication, 20%
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1
2
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Citations by publishers
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1
2
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World Scientific
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World Scientific
2 publications, 40%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 20%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 20%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 20%
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1
2
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Zvyagina A. I. et al. Ion-Driven Self-Assembly of Lanthanide Bis-phthalocyaninates into Conductive Quasi-MOF Nanowires: An Approach toward Easily Recyclable Organic Electronics // Inorganic Chemistry. 2021. Vol. 60. No. 20. pp. 15509-15518.
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Zvyagina A. I., Aleksandrov A., Martynov A. G., Tameev A., Baranchikov A. E., Ежов А. А., Gorbunova Y. G., Kalinina M. A. Ion-Driven Self-Assembly of Lanthanide Bis-phthalocyaninates into Conductive Quasi-MOF Nanowires: An Approach toward Easily Recyclable Organic Electronics // Inorganic Chemistry. 2021. Vol. 60. No. 20. pp. 15509-15518.
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TY - JOUR
DO - 10.1021/acs.inorgchem.1c02147
UR - https://doi.org/10.1021%2Facs.inorgchem.1c02147
TI - Ion-Driven Self-Assembly of Lanthanide Bis-phthalocyaninates into Conductive Quasi-MOF Nanowires: An Approach toward Easily Recyclable Organic Electronics
T2 - Inorganic Chemistry
AU - Zvyagina, Alexandra I
AU - Martynov, Alexander G.
AU - Tameev, Alexey
AU - Baranchikov, Alexander E
AU - Ежов, А. А.
AU - Gorbunova, Yulia G.
AU - Kalinina, Maria A
AU - Aleksandrov, Alexey
PY - 2021
DA - 2021/10/06 00:00:00
PB - American Chemical Society (ACS)
SP - 15509-15518
IS - 20
VL - 60
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2021_Zvyagina,
author = {Alexandra I Zvyagina and Alexander G. Martynov and Alexey Tameev and Alexander E Baranchikov and А. А. Ежов and Yulia G. Gorbunova and Maria A Kalinina and Alexey Aleksandrov},
title = {Ion-Driven Self-Assembly of Lanthanide Bis-phthalocyaninates into Conductive Quasi-MOF Nanowires: An Approach toward Easily Recyclable Organic Electronics},
journal = {Inorganic Chemistry},
year = {2021},
volume = {60},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021%2Facs.inorgchem.1c02147},
number = {20},
pages = {15509--15518},
doi = {10.1021/acs.inorgchem.1c02147}
}
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MLA
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Zvyagina, Alexandra I., et al. “Ion-Driven Self-Assembly of Lanthanide Bis-phthalocyaninates into Conductive Quasi-MOF Nanowires: An Approach toward Easily Recyclable Organic Electronics.” Inorganic Chemistry, vol. 60, no. 20, Oct. 2021, pp. 15509-15518. https://doi.org/10.1021%2Facs.inorgchem.1c02147.