Synthesis of Difluoroalkylated Heteroarenes via Difluorocarbene
Publication type: Journal Article
Publication date: 2021-08-24
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
34428070
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A diversity-oriented and C2-selective synthesis of difluoroalkyl-substituted heteroarenes from three fragments, N-methoxyazinium salts, difluorocarbene, and electrophilic or radical reagents, is described. The reaction proceeds via the addition of difluorinated phosphorus ylide to in situ methylated heteroarene N-oxides, leading to phosphonium salts, which can undergo further transformations under basic or photoinduced conditions.
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30
Total citations:
30
Citations from 2024:
15
(50%)
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MLA
Cite this
GOST
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Trifonov A. L., Dilman A. D. Synthesis of Difluoroalkylated Heteroarenes via Difluorocarbene // Organic Letters. 2021. Vol. 23. No. 17. pp. 6977-6981.
GOST all authors (up to 50)
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Trifonov A. L., Dilman A. D. Synthesis of Difluoroalkylated Heteroarenes via Difluorocarbene // Organic Letters. 2021. Vol. 23. No. 17. pp. 6977-6981.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.orglett.1c02603
UR - https://doi.org/10.1021/acs.orglett.1c02603
TI - Synthesis of Difluoroalkylated Heteroarenes via Difluorocarbene
T2 - Organic Letters
AU - Trifonov, Alexey L
AU - Dilman, Alexander D
PY - 2021
DA - 2021/08/24
PB - American Chemical Society (ACS)
SP - 6977-6981
IS - 17
VL - 23
PMID - 34428070
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Trifonov,
author = {Alexey L Trifonov and Alexander D Dilman},
title = {Synthesis of Difluoroalkylated Heteroarenes via Difluorocarbene},
journal = {Organic Letters},
year = {2021},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.orglett.1c02603},
number = {17},
pages = {6977--6981},
doi = {10.1021/acs.orglett.1c02603}
}
Cite this
MLA
Copy
Trifonov, Alexey L., and Alexander D Dilman. “Synthesis of Difluoroalkylated Heteroarenes via Difluorocarbene.” Organic Letters, vol. 23, no. 17, Aug. 2021, pp. 6977-6981. https://doi.org/10.1021/acs.orglett.1c02603.
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