Demonstrated 6-endo-tet Cyclizations!

G e o r g T h i e m e V e r l a g K G , R ü d i g e r s t r a ß e 1 4 , 7 0 4 6 9 S t u t t g a r t , G e r m a n y 1317 A . E . V A R T A N O V A , A . Y . P L O D U H K I N , N . K . R A T M A N O V A , I . A . A N D R E E V , M . N . A N I S I M O V , N . B . G U D I M C H U K , V . B . R Y B A K O V , I . I . L E V I N A , O . A . I V A N O V A * , I . V . T R U S H K O V * , I . V . A L A B U G I N * ( F L O R I D A S T A T E U N I V E R S I T Y , U S A ; N . D . Z E L I N S K Y I N S T I T U T E O F O R G A N I C C H E M I S T R Y , M O S C O W A N D M O S C O W S T A T E U N I V E R S I T Y , R U S S I A N F E D E R A T I O N ) Expanding Stereoelectronic Limits of endo-tet Cyclizations: Synthesis of Benz[b]azepines from Donor–Acceptor Cyclopropanes J. Am. Chem. Soc. 2021, 143, 13952–13961, DOI: 10.1021/jacs.1c07088.