Journal of Heterocyclic Chemistry, volume 45, issue 2, pages 497-502
High pressure-assisted synthesis of 1,2,3-trialkyldiaziridines from N-chloroalkylamines
V. V. Kuznetsov
1
,
Julia S Syroeshkina
1
,
Dmitrii I Moskvin
1
,
Marina I. Struchkova
1
,
Nina N. Makhova
1
,
Alexey A Zharov
1
Publication type: Journal Article
Publication date: 2008-03-01
Journal:
Journal of Heterocyclic Chemistry
Quartile SCImago
Q3
Quartile WOS
Q2
Impact factor: 2.4
ISSN: 0022152X, 19435193
Organic Chemistry
Abstract
New method for the preparation of 1,2,3-trialkyldiaziridines 1 in high yields, based on the transformation of N-chloroalkylamines 3 without using carbonyl compounds in the presence of primary aliphatic amines with the same alkyl fragment, potassium carbonate and a small amount of water in CHCl3 under high pressure (500 MPa), was developed. Diaziridines 1 can be synthesized in the same conditions using a larger amount of potassium carbonate instead of primary aliphatic amines however in lower yields. The kinetic investigations on the synthesis of 1,2-diethyl-3-methyldiaziridine 1a from N-chloroethylamine 3a have shown that the reaction leading to diaziridine 1a proceeds according to the law of the second order.
Top-30
Citations by journals
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1
2
3
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Journal of Heterocyclic Chemistry
3 publications, 37.5%
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Mendeleev Communications
1 publication, 12.5%
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Russian Journal of Physical Chemistry A
1 publication, 12.5%
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ChemInform
1 publication, 12.5%
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Organic and Biomolecular Chemistry
1 publication, 12.5%
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1
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3
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Citations by publishers
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1
2
3
4
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Wiley
4 publications, 50%
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Elsevier
2 publications, 25%
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Pleiades Publishing
1 publication, 12.5%
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Royal Society of Chemistry (RSC)
1 publication, 12.5%
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1
2
3
4
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kuznetsov V. V. et al. High pressure-assisted synthesis of 1,2,3-trialkyldiaziridines from N-chloroalkylamines // Journal of Heterocyclic Chemistry. 2008. Vol. 45. No. 2. pp. 497-502.
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Kuznetsov V. V., Syroeshkina J. S., Moskvin D. I., Struchkova M. I., Makhova N. N., Zharov A. A. High pressure-assisted synthesis of 1,2,3-trialkyldiaziridines from N-chloroalkylamines // Journal of Heterocyclic Chemistry. 2008. Vol. 45. No. 2. pp. 497-502.
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TY - JOUR
DO - 10.1002/jhet.5570450230
UR - https://doi.org/10.1002/jhet.5570450230
TI - High pressure-assisted synthesis of 1,2,3-trialkyldiaziridines from N-chloroalkylamines
T2 - Journal of Heterocyclic Chemistry
AU - Syroeshkina, Julia S
AU - Moskvin, Dmitrii I
AU - Struchkova, Marina I.
AU - Zharov, Alexey A
AU - Kuznetsov, V. V.
AU - Makhova, Nina N.
PY - 2008
DA - 2008/03/01 00:00:00
PB - Wiley
SP - 497-502
IS - 2
VL - 45
SN - 0022-152X
SN - 1943-5193
ER -
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@article{2008_Kuznetsov,
author = {Julia S Syroeshkina and Dmitrii I Moskvin and Marina I. Struchkova and Alexey A Zharov and V. V. Kuznetsov and Nina N. Makhova},
title = {High pressure-assisted synthesis of 1,2,3-trialkyldiaziridines from N-chloroalkylamines},
journal = {Journal of Heterocyclic Chemistry},
year = {2008},
volume = {45},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/jhet.5570450230},
number = {2},
pages = {497--502},
doi = {10.1002/jhet.5570450230}
}
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Kuznetsov, V. V., et al. “High pressure-assisted synthesis of 1,2,3-trialkyldiaziridines from N-chloroalkylamines.” Journal of Heterocyclic Chemistry, vol. 45, no. 2, Mar. 2008, pp. 497-502. https://doi.org/10.1002/jhet.5570450230.