Journal of Physical Chemistry A, volume 113, issue 29, pages 8143-8146
Conformation-dependent chemical reaction of formic acid with an oxygen atom
Domanskaya Alexandra
1
,
Marushkevich Kseniya
1
,
Räsänen Markku
1
,
Grigorenko Bella
1
,
Andrijchenko Natalya
1
,
Publication type: Journal Article
Publication date: 2009-07-01
Journal:
Journal of Physical Chemistry A
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.9
ISSN: 10895639, 15205215
Physical and Theoretical Chemistry
Abstract
Conformation dictates many physical and chemical properties of molecules. The importance of conformation in the selectivity and function of biologically active molecules is widely accepted. However, clear examples of conformation-dependent bimolecular chemical reactions are lacking. Here we consider a case of formic acid (HCOOH) that is a valuable model system containing the -COOH carboxyl functional group, similar to many biomolecules including the standard amino acids. We have found a strong case of conformation-dependent reaction between formic acid and atomic oxygen obtained in cryogenic matrices. The reaction surprisingly leads to peroxyformic acid only from the ground-state trans conformer of formic acid, and it results in the hydrogen-bonded complex for the higher-energy cis conformer.
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1 publication, 3.23%
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1 publication, 3.23%
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2
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Citations by publishers
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2
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14
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13 publications, 41.94%
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6 publications, 19.35%
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2 publications, 6.45%
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Wiley
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2 publications, 6.45%
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1 publication, 3.23%
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American Physical Society (APS)
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1 publication, 3.23%
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Springer Nature
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Springer Nature
1 publication, 3.23%
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Elsevier
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Elsevier
1 publication, 3.23%
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American Association for the Advancement of Science (AAAS)
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American Association for the Advancement of Science (AAAS)
1 publication, 3.23%
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2
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Khriachtchev L. et al. Conformation-dependent chemical reaction of formic acid with an oxygen atom // Journal of Physical Chemistry A. 2009. Vol. 113. No. 29. pp. 8143-8146.
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Khriachtchev L., Domanskaya A., Marushkevich K., Räsänen M., Grigorenko B., Ermilov A., Andrijchenko N., Nemukhin A. Conformation-dependent chemical reaction of formic acid with an oxygen atom // Journal of Physical Chemistry A. 2009. Vol. 113. No. 29. pp. 8143-8146.
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TY - JOUR
DO - 10.1021/jp903775k
UR - https://doi.org/10.1021%2Fjp903775k
TI - Conformation-dependent chemical reaction of formic acid with an oxygen atom
T2 - Journal of Physical Chemistry A
AU - Domanskaya, Alexandra
AU - Marushkevich, Kseniya
AU - Ermilov, Alexander
AU - Andrijchenko, Natalya
AU - Khriachtchev, Leonid
AU - Räsänen, Markku
AU - Grigorenko, Bella
AU - Nemukhin, Alexander
PY - 2009
DA - 2009/07/01 00:00:00
PB - American Chemical Society (ACS)
SP - 8143-8146
IS - 29
VL - 113
SN - 1089-5639
SN - 1520-5215
ER -
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@article{2009_Khriachtchev,
author = {Alexandra Domanskaya and Kseniya Marushkevich and Alexander Ermilov and Natalya Andrijchenko and Leonid Khriachtchev and Markku Räsänen and Bella Grigorenko and Alexander Nemukhin},
title = {Conformation-dependent chemical reaction of formic acid with an oxygen atom},
journal = {Journal of Physical Chemistry A},
year = {2009},
volume = {113},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021%2Fjp903775k},
number = {29},
pages = {8143--8146},
doi = {10.1021/jp903775k}
}
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MLA
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Khriachtchev, Leonid, et al. “Conformation-dependent chemical reaction of formic acid with an oxygen atom.” Journal of Physical Chemistry A, vol. 113, no. 29, Jul. 2009, pp. 8143-8146. https://doi.org/10.1021%2Fjp903775k.