Dalton Transactions, volume 48, issue 14, pages 4677-4684

P-Chiral 1,7-diphosphanorbornenes: from asymmetric phospha-Diels–Alder reactions towards applications in asymmetric catalysis

Almaz A Zagidullin 1, 2, 3, 4
E S Oshchepkova 1, 2, 3, 4
I V Chuchelkin 4, 5, 6
S A Kondrashova 1, 2, 3, 4
Vasili Miluykov 1, 2, 3, 4
Shamil Latypov 1, 2, 3, 4
Evamarie Hey-Hawkins 7, 8, 9, 10
3
 
Kazan
4
 
Russia
6
 
Ryazan
7
 
Institut für Anorganische Chemie
9
 
04103 Leipzig
10
 
GERMANY
Publication typeJournal Article
Publication date2019-03-12
scimago Q1
SJR0.697
CiteScore6.6
Impact factor3.5
ISSN14779226, 14779234
PubMed ID:  30895990
Inorganic Chemistry
Abstract

A straightforward synthesis of P-chiral polycyclic phosphines by an asymmetric Diels–Alder reaction of 1-alkyl-1,2-diphospholes and (5R)-(l-menthyloxy)-2(5H)-furanone (MOxF) is presented.

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