A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Laboratory of Organoaluminum and Organoboron Compounds

Organoelement chemistry

Head of Laboratory

Igor B Sivaev

DSc in Chemistry

Publications

235

Citations

5 849

h-index

Authorization required.

Synthesis and study of the reactivity of polyhedral boranes, carboranes and metallacarboranes. Development of new boron-containing materials and medicals.

NMR spectroscopy
X-ray diffraction analysis

Igor Sivaev

Head of Laboratory

Vladimir Bregadze

Principal researcher

Marina Stogniy

Senior Researcher

Sergey Anufriev

Senior Researcher

Akim Shmal'ko

Senior Researcher

Anna Druzina

Senior Researcher

Sergey Timofeev

Senior Researcher

Irina Kosenko

Researcher

Research directions

Study of the reactivity of polyhedral boranes, carboranes and metallacarboranes and development of methods for the synthesis of their various functional derivatives.

Although the chemistry of polyhedral boron compounds goes back over 60 years, along with well-trodden roads and well-explored areas, its map contains a large number of “blank spots” (“Terra incognita”), the exploration of which often becomes a real adventure.

Publications and patents

Boron-Containing Lipids and Liposomes: New Conjugates of Cholesterol with Polyhedral Boron Hydrides.

Chemistry - A European Journal (Q1), 2020, Citations: 34

Cyclic oxonium derivatives of cobalt and iron bis(dicarbollides) and their use in organic synthesis

Russian Chemical Reviews (Q1), 2021, Citations: 26

Synthesis and crystal structures of nickel(ii) and palladium(ii) complexes with o-carboranyl amidine ligands.

Dalton Transactions (Q2), 2021, Citations: 21

Bis(dicarbollide) Complexes of Transition Metals as a Platform for Molecular Switches. Study of Complexation of 8,8′-Bis(methylsulfanyl) Derivatives of Cobalt and Iron Bis(dicarbollides)

Molecules (Q1), 2020, Citations: 12

The unexpected reactivity of 9-iodo-nido-carborane: from nucleophilic substitution reactions to the synthesis of tricobalt tris(dicarbollide) Na[4,4′,4′′-(MeOCH₂CH₂O)₃-3,3′,3′′-Co₃(μ³-O)(μ³-S)(1,2-C₂B₉H₁₀)₃]

Dalton Transactions (Q2), 2021, Citations: 8

Charge-compensated nido-carborane derivatives in the synthesis of iron(II) bis(dicarbollide) complexes

Dalton Transactions (Q2), 2024, Citations: 5

Found

Lab address

г. Москва, ул. Вавилова, 28, стр. 1

Authorization required.

Laboratory of Organoaluminum and Organoboron Compounds

Igor B Sivaev

Research directions

Study of the reactivity of polyhedral boranes, carboranes and metallacarboranes and development of methods for the synthesis of their various functional derivatives.

Publications and patents

Boron-Containing Lipids and Liposomes: New Conjugates of Cholesterol with Polyhedral Boron Hydrides.

Cyclic oxonium derivatives of cobalt and iron bis(dicarbollides) and their use in organic synthesis

Synthesis and crystal structures of nickel(ii) and palladium(ii) complexes with o-carboranyl amidine ligands.

Bis(dicarbollide) Complexes of Transition Metals as a Platform for Molecular Switches. Study of Complexation of 8,8′-Bis(methylsulfanyl) Derivatives of Cobalt and Iron Bis(dicarbollides)

The unexpected reactivity of 9-iodo-nido-carborane: from nucleophilic substitution reactions to the synthesis of tricobalt tris(dicarbollide) Na[4,4′,4′′-(MeOCH2CH2O)3-3,3′,3′′-Co3(μ3-O)(μ3-S)(1,2-C2B9H10)3]

Charge-compensated nido-carborane derivatives in the synthesis of iron(II) bis(dicarbollide) complexes

Lab address

The unexpected reactivity of 9-iodo-nido-carborane: from nucleophilic substitution reactions to the synthesis of tricobalt tris(dicarbollide) Na[4,4′,4′′-(MeOCH₂CH₂O)₃-3,3′,3′′-Co₃(μ³-O)(μ³-S)(1,2-C₂B₉H₁₀)₃]