Angewandte Chemie - International Edition, volume 56, issue 28, pages 8236-8239

Enantiopure Cycloiridiated Complexes Bearing a Pentahelicenic N‐Heterocyclic Carbene and Displaying Long‐Lived Circularly Polarized Phosphorescence

Nora Hellou 1
, 
Monika Srebro‐Hooper 2
, 
Ludovic Favereau 1
, 
Francesco Zinna 3, 4
, 
Elsa Caytan 1
, 
Loïc Toupet 1
, 
Vincent Dorcet 1
, 
Marion Jean 5
, 
Nicolas Vanthuyne 5
, 
J.A. Gareth Williams 6
, 
L. Di Bari 3
, 
Jochen Autschbach 7
, 
Jeanne Crassous 1
Show full list: 13 authors
1
 
2
 
3
 
4
 
5
 
6
 
Department of Chemistry University of Durham Durham DH1 3LE UK | 
7
 
Publication type: Journal Article
Publication date: 2017-06-12
scimago Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
A fused π-helical N-heterocyclic system was prepared and examined through its enantiomerically and diastereoisomerically pure cycloiridiated complexes. The systems display long-lived circularly polarized phosphorescence, which is attributed to extended π conjugation within the helical carbenic ligand efficiently interacting with the IrIII center.
Found 
Found 

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