Institut de Physique de Rennes

Vallenari A., Brown A.G., Prusti T.

Context. We present the third data release of the European Space Agency’s Gaia mission, Gaia DR3. This release includes a large variety of new data products, notably a much expanded radial velocity survey and a very extensive astrophysical characterisation of Gaia sources. Aims. We outline the content and the properties of Gaia DR3, providing an overview of the main improvements in the data processing in comparison with previous data releases (where applicable) and a brief discussion of the limitations of the data in this release. Methods. The Gaia DR3 catalogue is the outcome of the processing of raw data collected with the Gaia instruments during the first 34 months of the mission by the Gaia Data Processing and Analysis Consortium. Results. The Gaia DR3 catalogue contains the same source list, celestial positions, proper motions, parallaxes, and broad band photometry in the G, GBP, and GRP pass-bands already present in the Early Third Data Release, Gaia EDR3. Gaia DR3 introduces an impressive wealth of new data products. More than 33 million objects in the ranges GRVS < 14 and 3100 < Teff < 14 500, have new determinations of their mean radial velocities based on data collected by Gaia. We provide GRVS magnitudes for most sources with radial velocities, and a line broadening parameter is listed for a subset of these. Mean Gaia spectra are made available to the community. The Gaia DR3 catalogue includes about 1 million mean spectra from the radial velocity spectrometer, and about 220 million low-resolution blue and red prism photometer BP/RP mean spectra. The results of the analysis of epoch photometry are provided for some 10 million sources across 24 variability types. Gaia DR3 includes astrophysical parameters and source class probabilities for about 470 million and 1500 million sources, respectively, including stars, galaxies, and quasars. Orbital elements and trend parameters are provided for some 800 000 astrometric, spectroscopic and eclipsing binaries. More than 150 000 Solar System objects, including new discoveries, with preliminary orbital solutions and individual epoch observations are part of this release. Reflectance spectra derived from the epoch BP/RP spectral data are published for about 60 000 asteroids. Finally, an additional data set is provided, namely the Gaia Andromeda Photometric Survey, consisting of the photometric time series for all sources located in a 5.5 degree radius field centred on the Andromeda galaxy. Conclusions. This data release represents a major advance with respect to Gaia DR2 and Gaia EDR3 because of the unprecedented quantity, quality, and variety of source astrophysical data. To date this is the largest collection of all-sky spectrophotometry, radial velocities, variables, and astrophysical parameters derived from both low- and high-resolution spectra and includes a spectrophotometric and dynamical survey of SSOs of the highest accuracy. The non-single star content surpasses the existing data by orders of magnitude. The quasar host and galaxy light profile collection is the first such survey that is all sky and space based. The astrophysical information provided in Gaia DR3 will unleash the full potential of Gaia’s exquisite astrometric, photometric, and radial velocity surveys.

McGuire B.A., Loomis R.A., Burkhardt A.M., Lee K.L., Shingledecker C.N., Charnley S.B., Cooke I.R., Cordiner M.A., Herbst E., Kalenskii S., Siebert M.A., Willis E.R., Xue C., Remijan A.J., McCarthy M.C.

Identifying PAHs in space Midinfrared spectroscopy has shown that polycyclic aromatic hydrocarbons (PAHs) are abundant in many astronomical objects, but this technique cannot determine which specific PAH molecules are present. Radio astronomy could provide individual identifications if the molecule is sufficiently abundant and has a large dipole moment, but PAHs are expected to produce large numbers of very weak lines. McGuire et al. performed a stacking and matched filter analysis to search for PAHs in radio observations of TMC-1, located within the interstellar Taurus Molecular Cloud. They identified emission from two isomers of the small PAH cyanonapthalene, two fused benzene rings with a CN group attached. Science , this issue p. 1265

Arenou F., Babusiaux C., Barstow M.

Context. The Gaia DR3 catalogue contains, for the first time, about 800 000 solutions with either orbital elements or trend parameters for astrometric, spectroscopic, and eclipsing binaries, and combinations of these three. Aims. With this paper, we aim to illustrate the huge potential of this large non-single-star catalogue. Methods. Using the orbital solutions and models of the binaries, we have built a catalogue of tens of thousands of stellar masses or lower limits thereof, some with consistent flux ratios. Properties concerning the completeness of the binary catalogues are discussed, statistical features of the orbital elements are explained, and a comparison with other catalogues is performed. Results. Illustrative applications are proposed for binaries across the Hertzsprung-Russell Diagram (HRD). Binarity is studied in the giant branch and a search for genuine spectroscopic binaries among long-period variables is performed. The discovery of new EL CVn systems illustrates the potential of combining variability and binarity catalogues. Potential compact object companions are presented, mainly white dwarf companions or double degenerates, but one candidate neutron star is also found. Towards the bottom of the main sequence, the orbits of previously suspected binary ultracool dwarfs are determined and new candidate binaries are discovered. The long awaited contribution of Gaia to the analysis of the substellar regime shows the brown dwarf desert around solar-type stars using true rather than minimum masses, and provides new important constraints on the occurrence rates of substellar companions to M dwarfs. Several dozen new exoplanets are proposed, including two with validated orbital solutions and one super-Jupiter orbiting a white dwarf, all being candidates requiring confirmation. Besides binarity, higher order multiple systems are also found. Conclusions. By increasing the number of known binary orbits by more than one order of magnitude, Gaia DR3 will provide a rich reservoir of dynamical masses and an important contribution to the analysis of stellar multiplicity.

Recio-Blanco A., de Laverny P., Palicio P.A., Kordopatis G.

Context. The chemo-physical parametrisation of stellar spectra is essential for understanding the nature and evolution of stars and of Galactic stellar populations. A worldwide observational effort from the ground has provided, in one century, an extremely heterogeneous collection of chemical abundances for about two million stars in total, with fragmentary sky coverage. Aims. This situation is revolutionised by the Gaia third data release (DR3), which contains the parametrisation of Radial Velocity Spectrometer (RVS) data performed by the General Stellar Parametriser-spectroscopy, GSP-Spec, module. Here we describe the parametrisation of the first 34 months of Gaia RVS observations. Methods. GSP-Spec estimates the chemo-physical parameters from combined RVS spectra of single stars, without additional inputs from astrometric, photometric, or spectro-photometric BP/RP data. The main analysis workflow described here, MatisseGauguin, is based on projection and optimisation methods and provides the stellar atmospheric parameters; the individual chemical abundances of N, Mg, Si, S, Ca, Ti, Cr, Fe I, Fe II, Ni, Zr, Ce and Nd; the differential equivalent width of a cyanogen line; and the parameters of a diffuse interstellar band (DIB) feature. Another workflow, based on an artificial neural network (ANN) and referred to with the same acronym, provides a second set of atmospheric parameters that are useful for classification control. For both workflows, we implement a detailed quality flag chain considering different error sources. Results. With about 5.6 million stars, the Gaia DR3 GSP-Spec all-sky catalogue is the largest compilation of stellar chemo-physical parameters ever published and the first one from space data. Internal and external biases have been studied taking into account the implemented flags. In some cases, simple calibrations with low degree polynomials are suggested. The homogeneity and quality of the estimated parameters enables chemo-dynamical studies of Galactic stellar populations, interstellar extinction studies from individual spectra, and clear constraints on stellar evolution models. We highly recommend that users adopt the provided quality flags for scientific exploitation. Conclusions. The Gaia DR3 GSP-Spec catalogue is a major step in the scientific exploration of Milky Way stellar populations. It will be followed by increasingly large and higher quality catalogues in future data releases, confirming the Gaia promise of a new Galactic vision.

Cammarata M., Zerdane S., Balducci L., Azzolina G., Mazerat S., Exertier C., Trabuco M., Levantino M., Alonso-Mori R., Glownia J.M., Song S., Catala L., Mallah T., Matar S.F., Collet E.

Photoinduced charge-transfer is an important process in nature and technology and is responsible for the emergence of exotic functionalities, such as magnetic order for cyanide-bridged bimetallic coordination networks. Despite its broad interest and intensive developments in chemistry and material sciences, the atomic-scale description of the initial photoinduced process, which couples intermetallic charge-transfer and spin transition, has been debated for decades; it has been beyond reach due to its extreme speed. Here we study this process in a prototype cyanide-bridged CoFe system by femtosecond X-ray and optical absorption spectroscopies, enabling the disentanglement of ultrafast electronic and structural dynamics. Our results demonstrate that it is the spin transition that occurs first on the Co site within ~50 fs, and it is this that drives the subsequent Fe-to-Co charge-transfer within ~200 fs. This study represents a step towards understanding and controlling charge-transfer-based functions using light. Cyanide-bridged CoFe coordination networks exhibit photomagnetism because of coupled charge-transfer and spin transition. Now, femtosecond X-ray and optical absorption spectroscopies have enabled the electronic and structural dynamics of this light-induced process to be disentangled and show that it is the spin transition on the cobalt atom, occurring within ~50 fs, that induces the Fe-to-Co charge-transfer within ~200 fs.

Andrae R., Fouesneau M., Sordo R., Bailer-Jones C.A., Dharmawardena T., Rybizki J., De Angeli F., Lindstrom H.E., Marshall D., Drimmel R., Korn A.J., Soubiran C., Brouillet N., Casamiquela L.

Context. The astrophysical characterisation of sources is among the major new data products in the third Gaia Data Release (DR3). In particular, there are stellar parameters for 471 million sources estimated from low-resolution BP/RP spectra. Aims. We present the General Stellar Parameterizer from Photometry (GSP-Phot), which is part of the astrophysical parameters inference system (Apsis). GSP-Phot is designed to produce a homogeneous catalogue of parameters for hundreds of millions of single non-variable stars based on their astrometry, photometry, and low-resolution BP/RP spectra. These parameters are effective temperature, surface gravity, metallicity, absolute MG magnitude, radius, distance, and extinction for each star. Methods. GSP-Phot uses a Bayesian forward-modelling approach to simultaneously fit the BP/RP spectrum, parallax, and apparent G magnitude. A major design feature of GSP-Phot is the use of the apparent flux levels of BP/RP spectra to derive, in combination with isochrone models, tight observational constraints on radii and distances. We carefully validate the uncertainty estimates by exploiting repeat Gaia observations of the same source. Results. The data release includes GSP-Phot results for 471 million sources with G <  19. Typical differences to literature values are 110 K for Teff and 0.2–0.25 for log g, but these depend strongly on data quality. In particular, GSP-Phot results are significantly better for stars with good parallax measurements (ϖ/σϖ >  20), mostly within 2 kpc. Metallicity estimates exhibit substantial biases compared to literature values and are only useful at a qualitative level. However, we provide an empirical calibration of our metallicity estimates that largely removes these biases. Extinctions A0 and ABP show typical differences from reference values of 0.07–0.09 mag. MCMC samples of the parameters are also available for 95% of the sources. Conclusions. GSP-Phot provides a homogeneous catalogue of stellar parameters, distances, and extinctions that can be used for various purposes, such as sample selections (OB stars, red giants, solar analogues etc.). In the context of asteroseismology or ground-based interferometry, where targets are usually bright and have good parallax measurements, GSP-Phot results should be particularly useful for combined analysis or target selection.

Creevey O., Sordo R., Pailler F.

Gaia Data Release 3 contains a wealth of new data products for the community. Astrophysical parameters are a major component of this release, and were produced by the Astrophysical parameters inference system (Apsis) within the Gaia Data Processing and Analysis Consortium (DPAC). The aim of this paper is to describe the overall content of the astrophysical parameters in Gaia DR3 and how they were produced. In Apsis, we use the mean BP/RP and mean RVS spectra along with astrometry and photometry, and we derive the following parameters: source classification and probabilities for 1.6 billion objects; interstellar medium characterisation and distances for up to 470 million sources, including a 2D total Galactic extinction map; 6 million redshifts of quasar candidates; 1.4 million redshifts of galaxy candidates; and an analysis of 50 million outlier sources through an unsupervised classification. The astrophysical parameters also include many stellar spectroscopic and evolutionary parameters for up to 470 million sources. These comprise Teff, log g, and [M/H] (470 million using BP/RP, 6 million using RVS), radius (470 million), mass (140 million), age (120 million), chemical abundances (up to 5 million), diffuse interstellar band analysis (0.5 million), activity indices (2 million), Hα equivalent widths (200 million), and further classification of spectral types (220 million) and emission-line stars (50 000). This paper is the first in a series of three papers, and focusses on describing the global content of the parameters in Gaia DR3. The accompanying Papers II and III focus on the validation and use of the stellar and non-stellar products, respectively. This catalogue is the most extensive homogeneous database of astrophysical parameters to date, and is based uniquely on Gaia data. It will only be superseded by Gaia Data Release 4, and will therefore remain a key reference over the next four years, providing astrophysical parameters independent of other ground- and space-based data.

Ram R., Xia L., Benzidi H., Guha A., Golovanova V., Garzón Manjón A., Llorens Rauret D., Sanz Berman P., Dimitropoulos M., Mundet B., Pastor E., Celorrio V., Mesa C.A., Das A.M., Pinilla-Sánchez A., et. al.

The oxygen evolution reaction is the bottleneck to energy-efficient water-based electrolysis for the production of hydrogen and other solar fuels. In proton exchange membrane water electrolysis (PEMWE), precious metals have generally been necessary for the stable catalysis of this reaction. In this work, we report that delamination of cobalt tungstate enables high activity and durability through the stabilization of oxide and water-hydroxide networks of the lattice defects in acid. The resulting catalysts achieve lower overpotentials, a current density of 1.8 amperes per square centimeter at 2 volts, and stable operation up to 1 ampere per square centimeter in a PEMWE system at industrial conditions (80°C) at 1.77 volts; a threefold improvement in activity; and stable operation at 1 ampere per square centimeter over the course of 600 hours.

Drimmel R., Romero-Gómez M., Chemin L., Ramos P., Poggio E., Ripepi V., Andrae R., Blomme R., Cantat-Gaudin T., Castro-Ginard A., Clementini G., Fiqueras F., Frémat Y., Fousneau M., Jardin K., et. al.

Context. With the most recent Gaia data release, the number of sources with complete 6D phase space information (position and velocity) has increased to well over 33 million stars, while stellar astrophysical parameters are provided for more than 470 million sources, and more than 11 million variable stars are identified. Aims. Using the astrophysical parameters and variability classifications provided in Gaia DR3, we selected various stellar populations to explore and identify non-axisymmetric features in the disc of the Milky Way in configuration and velocity space. Methods. Using more about 580 000 sources identified as hot OB stars, together with 988 known open clusters younger than 100 Myr, we mapped the spiral structure associated with star formation 4−5 kpc from the Sun. We selected over 2800 Classical Cepheids younger than 200 Myr that show spiral features extending as far as 10 kpc from the Sun in the outer disc. We also identified more than 8.7 million sources on the red giant branch (RGB), of which 5.7 million have line-of-sight velocities. This later sample allows the velocity field of the Milky Way to be mapped as far as 8 kpc from the Sun, including the inner disc. Results. The spiral structure revealed by the young populations is consistent with recent results using Gaia EDR3 astrometry and source lists based on near-infrared photometry, showing the Local (Orion) Arm to be at least 8 kpc long, and an outer arm consistent with what is seen in HI surveys, which seems to be a continuation of the Perseus arm into the third quadrant. The subset of RGB stars with velocities clearly reveals the large-scale kinematic signature of the bar in the inner disc, as well as evidence of streaming motions in the outer disc that might be associated with spiral arms or bar resonances. A local comparison of the velocity field of the OB stars reveals similarities and differences with the RGB sample. Conclusions. This cursory study of Gaia DR3 data shows there is a rich bounty of kinematic information to be explored more deeply, which will undoubtedly lead us to a clearer understanding of the dynamical nature of the non-axisymmetric structures of the Milky Way.

Rowe B.R., Canosa A., Drouffe J.M., Mitchell J.B.

In this paper we develop a simple model of the inhaled flow rate of aerosol particles of respiratory origin i.e. that have been exhaled by other people. A connection is made between the exposure dose and the probability of developing an airborne disease. This allows a simple assessment of the outdoor versus indoor risk of contamination to be made in a variety of meteorological situations. It is shown quantitatively that for most cases, the outdoor risk is orders of magnitude less than the indoor risk and that it can become comparable only for extremely specific meteorological and topographical situations. It sheds light on various observations of COVID-19 spreading in mountain valleys with temperature inversions while at the same time other areas are much less impacted.