Angewandte Chemie - International Edition, volume 58, issue 20, pages 6727-6731
Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode.
Buhaibeh Ruqaya
1
,
Filippov Oleg A.
2
,
Bruneau Voisine Antoine
1, 3
,
Willot Jérémy
1
,
Duhayon Carine
1
,
Valyaev D. A.
1
,
Lugan Noël
1
,
Canac Yves
1
,
1
LCC-CNRSUniversité de Toulouse, CNRSUPS 205 route de Narbonne 31077 Toulouse Cedex 4 France
|
3
Univ RennesCNRS, ISCR—UMR 6226 35000 Rennes France
|
4
Institut Universitaire de France 1 rue Descartes 75231 Paris Cedex 05 France
|
Publication type: Journal Article
Publication date: 2019-05-13
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
Deprotonation of the MnI NHC-phosphine complex fac-[MnBr(CO)3 (κ2 P,C-Ph2 PCH2 NHC)] (2) under a H2 atmosphere readily gives the hydride fac-[MnH(CO)3 (κ2 P,C-Ph2 PCH2 NHC)] (3) via the intermediacy of the highly reactive 18-e NHC-phosphinomethanide complex fac-[Mn(CO)3 (κ3 P,C,C-Ph2 PCHNHC)] (6 a). DFT calculations revealed that the preferred reaction mechanism involves the unsaturated 16-e mangana-substituted phosphonium ylide complex fac-[Mn(CO)3 (κ2 P,C-Ph2 P=CHNHC)] (6 b) as key intermediate able to activate H2 via a non-classical mode of metal-ligand cooperation implying a formal λ5 -P-λ3 -P phosphorus valence change. Complex 2 is shown to be one of the most efficient pre-catalysts for ketone hydrogenation in the MnI series reported to date (TON up to 6200).
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Buhaibeh R. et al. Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode. // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 20. pp. 6727-6731.
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Buhaibeh R., Filippov O. A., Bruneau Voisine A., Willot J., Duhayon C., Valyaev D. A., Lugan N., Canac Y., Sortais J. Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode. // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 20. pp. 6727-6731.
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TY - JOUR
DO - 10.1002/anie.201901169
UR - https://doi.org/10.1002%2Fanie.201901169
TI - Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode.
T2 - Angewandte Chemie - International Edition
AU - Willot, Jérémy
AU - Filippov, Oleg A.
AU - Bruneau Voisine, Antoine
AU - Duhayon, Carine
AU - Valyaev, D. A.
AU - Lugan, Noël
AU - Canac, Yves
AU - Sortais, Jean-Baptiste
AU - Buhaibeh, Ruqaya
PY - 2019
DA - 2019/05/13 00:00:00
PB - Wiley
SP - 6727-6731
IS - 20
VL - 58
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2019_Buhaibeh,
author = {Jérémy Willot and Oleg A. Filippov and Antoine Bruneau Voisine and Carine Duhayon and D. A. Valyaev and Noël Lugan and Yves Canac and Jean-Baptiste Sortais and Ruqaya Buhaibeh},
title = {Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode.},
journal = {Angewandte Chemie - International Edition},
year = {2019},
volume = {58},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002%2Fanie.201901169},
number = {20},
pages = {6727--6731},
doi = {10.1002/anie.201901169}
}
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MLA
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Buhaibeh, Ruqaya, et al. “Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode..” Angewandte Chemie - International Edition, vol. 58, no. 20, May. 2019, pp. 6727-6731. https://doi.org/10.1002%2Fanie.201901169.