Nitro and Other Electron Withdrawing Group Activated Ruthenium Catalysts for Olefin Metathesis Reactions
Karol Grela
1, 2
Тип публикации: Journal Article
Дата публикации: 2020-12-03
scimago Q1
wos Q1
БС1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
32808704
General Chemistry
Catalysis
Краткое описание
Advanced applications of the Nobel Prize winning olefin metathesis reaction require user-friendly and highly universal catalysts. From many successful metathesis catalysts, which belong to the two distinct classes of Schrock and Grubbs-type catalysts, the subclass of chelating-benzylidene ruthenium complexes (so-called Hoveyda-Grubbs catalysts) additionally activated by electron-withdrawing groups (EWGs) provides a highly tunable platform. In the Review, the origin of the EWG-activation concept and selected applications of the resulting catalysts in target-oriented synthesis, medicinal chemistry, as well as in the preparation of fine-chemicals and in materials chemistry is discussed. Based on the examples, some suggestions for end-users regarding minimization of catalyst loading, selectivity control, and general optimization of the olefin metathesis reaction are provided.
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Kajetanowicz A., Grela K. Nitro and Other Electron Withdrawing Group Activated Ruthenium Catalysts for Olefin Metathesis Reactions // Angewandte Chemie - International Edition. 2020. Vol. 60. No. 25. pp. 13738-13756.
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Kajetanowicz A., Grela K. Nitro and Other Electron Withdrawing Group Activated Ruthenium Catalysts for Olefin Metathesis Reactions // Angewandte Chemie - International Edition. 2020. Vol. 60. No. 25. pp. 13738-13756.
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TY - JOUR
DO - 10.1002/anie.202008150
UR - https://doi.org/10.1002/anie.202008150
TI - Nitro and Other Electron Withdrawing Group Activated Ruthenium Catalysts for Olefin Metathesis Reactions
T2 - Angewandte Chemie - International Edition
AU - Kajetanowicz, Anna
AU - Grela, Karol
PY - 2020
DA - 2020/12/03
PB - Wiley
SP - 13738-13756
IS - 25
VL - 60
PMID - 32808704
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2020_Kajetanowicz,
author = {Anna Kajetanowicz and Karol Grela},
title = {Nitro and Other Electron Withdrawing Group Activated Ruthenium Catalysts for Olefin Metathesis Reactions},
journal = {Angewandte Chemie - International Edition},
year = {2020},
volume = {60},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/anie.202008150},
number = {25},
pages = {13738--13756},
doi = {10.1002/anie.202008150}
}
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Kajetanowicz, Anna, et al. “Nitro and Other Electron Withdrawing Group Activated Ruthenium Catalysts for Olefin Metathesis Reactions.” Angewandte Chemie - International Edition, vol. 60, no. 25, Dec. 2020, pp. 13738-13756. https://doi.org/10.1002/anie.202008150.