Organotin polymers. IV. Binary and ternary copolymerizations of tributyltin acrylate and methacrylate with styrene, allyl methacrylate, butyl methacrylate, butyl acrylate, and acrylonitrile
Publication type: Journal Article
Publication date: 1981-01-01
scimago Q2
wos Q3
SJR: 0.572
CiteScore: 5.8
Impact factor: 2.8
ISSN: 00218995, 10974628
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Polymers and Plastics
Abstract
The monomer reactivity ratios for the copolymerization of tributyltin acrylate with styrene and allyl methacrylate have been found to be r1 = 0.213, r2 = 1.910 and r1 = 0.195, r2 = 2.257, respectively. Also, the copolymerization parameters of tributyltin methacrylate with styrene and allyl methacrylate were as follows: r1 = 0.256, r2 = 1.104 and r1 = 2.306, r2 = 1.013. Copolymerization reactions were carried out in solution at 70°C using 1 mole % AIBN, and the copolymer compositions were determined by tin analysis. Ternary copolymerization of the three systems butyl methacrylate–tributyltin methacrylate–acrylonitrile, butyl acrylate–tributyltin methacrylate–acrylonitrile, and styrene–tributyltin acrylate–acrylonitrile have been studied, and the terpolymer composition of each system was determined through tin and nitrogen analyses. The variation of instantaneous and average terpolymer composition with conversion fit satisfactorily the experimental results over a wide range of conversion.
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Ghanem N. (. et al. Organotin polymers. IV. Binary and ternary copolymerizations of tributyltin acrylate and methacrylate with styrene, allyl methacrylate, butyl methacrylate, butyl acrylate, and acrylonitrile // Journal of Applied Polymer Science. 1981. Vol. 26. No. 1. pp. 97-106.
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Ghanem N. (., Messiha N., Ikladious N., Shaaban A. Organotin polymers. IV. Binary and ternary copolymerizations of tributyltin acrylate and methacrylate with styrene, allyl methacrylate, butyl methacrylate, butyl acrylate, and acrylonitrile // Journal of Applied Polymer Science. 1981. Vol. 26. No. 1. pp. 97-106.
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TY - JOUR
DO - 10.1002/app.1981.070260109
UR - https://doi.org/10.1002/app.1981.070260109
TI - Organotin polymers. IV. Binary and ternary copolymerizations of tributyltin acrylate and methacrylate with styrene, allyl methacrylate, butyl methacrylate, butyl acrylate, and acrylonitrile
T2 - Journal of Applied Polymer Science
AU - Ghanem, N (a)
AU - Messiha, N.N.
AU - Ikladious, N.E
AU - Shaaban, A.F.
PY - 1981
DA - 1981/01/01
PB - Wiley
SP - 97-106
IS - 1
VL - 26
SN - 0021-8995
SN - 1097-4628
ER -
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BibTex (up to 50 authors)
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@article{1981_Ghanem,
author = {N (a) Ghanem and N.N. Messiha and N.E Ikladious and A.F. Shaaban},
title = {Organotin polymers. IV. Binary and ternary copolymerizations of tributyltin acrylate and methacrylate with styrene, allyl methacrylate, butyl methacrylate, butyl acrylate, and acrylonitrile},
journal = {Journal of Applied Polymer Science},
year = {1981},
volume = {26},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/app.1981.070260109},
number = {1},
pages = {97--106},
doi = {10.1002/app.1981.070260109}
}
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MLA
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Ghanem, N. (a), et al. “Organotin polymers. IV. Binary and ternary copolymerizations of tributyltin acrylate and methacrylate with styrene, allyl methacrylate, butyl methacrylate, butyl acrylate, and acrylonitrile.” Journal of Applied Polymer Science, vol. 26, no. 1, Jan. 1981, pp. 97-106. https://doi.org/10.1002/app.1981.070260109.