volume 17 issue 18 pages 5045-5053

Olefin Metathesis Featuring Ruthenium Indenylidene Complexes with a Sterically Demanding NHC Ligand

Publication typeJournal Article
Publication date2011-03-23
scimago Q1
wos Q2
SJR0.981
CiteScore6.7
Impact factor3.7
ISSN09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
The synthesis and characterization of two new ruthenium indenylidene complexes [RuCl(2)(SIPr)(Py)(Ind)] 6 and [RuCl(2)(SIPr)(3-BrPy)(Ind)] 7 featuring the sterically demanding N-heterocyclic carbene 1,3-bis(2,6-di isopropylphenyl)-4,5-dihydroimidazol-2-ylidene (SIPr) are reported. Remarkable activity was observed with these complexes in ring closing, enyne, and cross metathesis of olefins at low catalyst loadings. The performance of SIPr-bearing complexes 6 and 7 as well as [RuCl(2)(SIPr)(PCy(3))(Ind)] 5 in ring opening metathesis polymerization is also disclosed. This work highlights the enormous influence of the neutral "spectator" ligands on catalyst activity and stability.
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GOST |
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GOST Copy
Urbina-Blanco C. A. et al. Olefin Metathesis Featuring Ruthenium Indenylidene Complexes with a Sterically Demanding NHC Ligand // Chemistry - A European Journal. 2011. Vol. 17. No. 18. pp. 5045-5053.
GOST all authors (up to 50) Copy
Urbina-Blanco C. A., Leitgeb A., Slugovc C., Lamaty F., CLAVIER H., Slawin A. M. Z., Nolan S. P. Olefin Metathesis Featuring Ruthenium Indenylidene Complexes with a Sterically Demanding NHC Ligand // Chemistry - A European Journal. 2011. Vol. 17. No. 18. pp. 5045-5053.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/chem.201003082
UR - https://doi.org/10.1002/chem.201003082
TI - Olefin Metathesis Featuring Ruthenium Indenylidene Complexes with a Sterically Demanding NHC Ligand
T2 - Chemistry - A European Journal
AU - Urbina-Blanco, César A.
AU - Leitgeb, Anita
AU - Slugovc, Christian
AU - Lamaty, Frédéric
AU - CLAVIER, HERVÉ
AU - Slawin, Alexandra M. Z.
AU - Nolan, Steven P.
PY - 2011
DA - 2011/03/23
PB - Wiley
SP - 5045-5053
IS - 18
VL - 17
PMID - 21433125
SN - 0947-6539
SN - 1521-3765
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2011_Urbina-Blanco,
author = {César A. Urbina-Blanco and Anita Leitgeb and Christian Slugovc and Frédéric Lamaty and HERVÉ CLAVIER and Alexandra M. Z. Slawin and Steven P. Nolan},
title = {Olefin Metathesis Featuring Ruthenium Indenylidene Complexes with a Sterically Demanding NHC Ligand},
journal = {Chemistry - A European Journal},
year = {2011},
volume = {17},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/chem.201003082},
number = {18},
pages = {5045--5053},
doi = {10.1002/chem.201003082}
}
MLA
Cite this
MLA Copy
Urbina-Blanco, César A., et al. “Olefin Metathesis Featuring Ruthenium Indenylidene Complexes with a Sterically Demanding NHC Ligand.” Chemistry - A European Journal, vol. 17, no. 18, Mar. 2011, pp. 5045-5053. https://doi.org/10.1002/chem.201003082.