Cationic Bis‐N‐Heterocyclic Carbene (NHC) Ruthenium Complex: Structure and Application as Latent Catalyst in Olefin Metathesis
Mathieu Rouen
1
,
Pierre Queval
1
,
Laura Falivene
2
,
Jessica Allard
1
,
Loïc Toupet
3
,
C. Crevisy
1
,
Fréderic Caijo
4
,
Olivier Baslé
1
,
Luigi Maria Cavallo
2, 5
,
Marc Mauduit
1
3
4
OmegaCat System, 11 Allée de Beaulieu, CS 50837, 35708, Rennes Cedex 7 (France)
|
Publication type: Journal Article
Publication date: 2014-09-11
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
25212827
General Chemistry
Catalysis
Organic Chemistry
Abstract
An unexpected cationic bis-N-heterocyclic carbene (NHC) benzylidene ether based ruthenium complex (2 a) was prepared through the double incorporation of an unsymmetrical unsaturated N-heterocyclic carbene (U2 -NHC) ligand that bore an N-substituted cyclododecyl side chain. The isolation and full characterization (including X-ray diffraction studies) of key synthetic intermediates along with theoretical calculations allowed us to understand the mechanism of the overall cationization process. Finally, the newly developed complex 2 a displayed interesting latent behavior during ring-closing metathesis, which could be "switched on" under acidic conditions.
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Total citations:
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Citations from 2024:
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GOST
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Rouen M. et al. Cationic Bis‐N‐Heterocyclic Carbene (NHC) Ruthenium Complex: Structure and Application as Latent Catalyst in Olefin Metathesis // Chemistry - A European Journal. 2014. Vol. 20. No. 42. pp. 13716-13721.
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Rouen M., Queval P., Falivene L., Allard J., Toupet L., Crevisy C., Caijo F., Baslé O., Cavallo L. M., Mauduit M. Cationic Bis‐N‐Heterocyclic Carbene (NHC) Ruthenium Complex: Structure and Application as Latent Catalyst in Olefin Metathesis // Chemistry - A European Journal. 2014. Vol. 20. No. 42. pp. 13716-13721.
Cite this
RIS
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TY - JOUR
DO - 10.1002/chem.201403934
UR - https://doi.org/10.1002/chem.201403934
TI - Cationic Bis‐N‐Heterocyclic Carbene (NHC) Ruthenium Complex: Structure and Application as Latent Catalyst in Olefin Metathesis
T2 - Chemistry - A European Journal
AU - Rouen, Mathieu
AU - Queval, Pierre
AU - Falivene, Laura
AU - Allard, Jessica
AU - Toupet, Loïc
AU - Crevisy, C.
AU - Caijo, Fréderic
AU - Baslé, Olivier
AU - Cavallo, Luigi Maria
AU - Mauduit, Marc
PY - 2014
DA - 2014/09/11
PB - Wiley
SP - 13716-13721
IS - 42
VL - 20
PMID - 25212827
SN - 0947-6539
SN - 1521-3765
ER -
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BibTex (up to 50 authors)
Copy
@article{2014_Rouen,
author = {Mathieu Rouen and Pierre Queval and Laura Falivene and Jessica Allard and Loïc Toupet and C. Crevisy and Fréderic Caijo and Olivier Baslé and Luigi Maria Cavallo and Marc Mauduit},
title = {Cationic Bis‐N‐Heterocyclic Carbene (NHC) Ruthenium Complex: Structure and Application as Latent Catalyst in Olefin Metathesis},
journal = {Chemistry - A European Journal},
year = {2014},
volume = {20},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/chem.201403934},
number = {42},
pages = {13716--13721},
doi = {10.1002/chem.201403934}
}
Cite this
MLA
Copy
Rouen, Mathieu, et al. “Cationic Bis‐N‐Heterocyclic Carbene (NHC) Ruthenium Complex: Structure and Application as Latent Catalyst in Olefin Metathesis.” Chemistry - A European Journal, vol. 20, no. 42, Sep. 2014, pp. 13716-13721. https://doi.org/10.1002/chem.201403934.