Chemical Record, volume 21, issue 9, pages 2148-2163

Electrochemical Insight into Mechanisms and Metallocyclic Intermediates of C−H Functionalization

Budnikova Yulia H. ^{1, 2}

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Arbuzov Institute of Organic and Physical Chemistry FRC Kazan Scientific Center of RAS Arbuzov Str. 8 420088 Kazan Russia

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Kazan National Research Technological University Karl Marx street, 68 420015 Kazan Russia |

Publication type: Journal Article

Publication date: 2021-02-25

Wiley

Journal: Chemical Record

Quartile SCImago

Quartile WOS

Impact factor: 6.6

ISSN: 15278999, 15280691

DOI: 10.1002/tcr.202100009

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Materials Chemistry

General Chemistry

Biochemistry

General Chemical Engineering

Abstract

Transition metal-catalyzed C-H activation has emerged as a powerful tool in organic synthesis and electrosynthesis as well as in the development of new methodologies for producing fine chemicals. In order to achieve efficient and selective C-H functionalization, different strategies have been used to accelerate the C-H activation step, including the incorporation of directing groups in the substrate that facilitate coordination to the catalyst. In this review, we try to underscore that the understanding the mechanisms of the catalytic cycle and the reactivity or redox activity of the key metal cyclic intermediates in these reactions is the basis for controlling the selectivity of synthesis and electrosynthesis. Combination of the electrosynthesis and voltammetry with traditional synthetic and physico-chemical methods allows one to achieve selective transformation of C-H bonds to functionalized C-C or C-X (X=heteroatom or halogen) bonds which may encourage organic chemists to use it in the future more often. The possibilities and the benefits of electrochemical techniques are analyzed and summarized.

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Citations by journals

	1 2
Frontiers in Chemistry	Frontiers in Chemistry, 2, 20% Frontiers in Chemistry 2 publications, 20%
Electrochimica Acta	Electrochimica Acta, 1, 10% Electrochimica Acta 1 publication, 10%
Journal of Solid State Electrochemistry	Journal of Solid State Electrochemistry, 1, 10% Journal of Solid State Electrochemistry 1 publication, 10%
Russian Journal of General Chemistry	Russian Journal of General Chemistry, 1, 10% Russian Journal of General Chemistry 1 publication, 10%
Chemical Communications	Chemical Communications, 1, 10% Chemical Communications 1 publication, 10%
Advances in Heterocyclic Chemistry	Advances in Heterocyclic Chemistry, 1, 10% Advances in Heterocyclic Chemistry 1 publication, 10%
Russian Journal of Electrochemistry	Russian Journal of Electrochemistry, 1, 10% Russian Journal of Electrochemistry 1 publication, 10%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 10% Russian Chemical Reviews 1 publication, 10%
	1 2

Citations by publishers

	1 2
Frontiers Media S.A.	Frontiers Media S.A., 2, 20% Frontiers Media S.A. 2 publications, 20%
Elsevier	Elsevier, 2, 20% Elsevier 2 publications, 20%
Pleiades Publishing	Pleiades Publishing, 2, 20% Pleiades Publishing 2 publications, 20%
Springer Nature	Springer Nature, 1, 10% Springer Nature 1 publication, 10%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 10% Royal Society of Chemistry (RSC) 1 publication, 10%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 10% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 10%
	1 2

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Budnikova Y. H. Electrochemical Insight into Mechanisms and Metallocyclic Intermediates of C−H Functionalization // Chemical Record. 2021. Vol. 21. No. 9. pp. 2148-2163.

GOST all authors (up to 50) Copy

Budnikova Y. H. Electrochemical Insight into Mechanisms and Metallocyclic Intermediates of C−H Functionalization // Chemical Record. 2021. Vol. 21. No. 9. pp. 2148-2163.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/tcr.202100009

UR - https://doi.org/10.1002%2Ftcr.202100009

TI - Electrochemical Insight into Mechanisms and Metallocyclic Intermediates of C−H Functionalization

T2 - Chemical Record

AU - Budnikova, Yulia H.

PY - 2021

DA - 2021/02/25 00:00:00

PB - Wiley

SP - 2148-2163

IS - 9

VL - 21

SN - 1527-8999

SN - 1528-0691

ER -

BibTex |

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BibTex Copy

@article{2021_Budnikova,

author = {Yulia H. Budnikova},

title = {Electrochemical Insight into Mechanisms and Metallocyclic Intermediates of C−H Functionalization},

journal = {Chemical Record},

year = {2021},

volume = {21},

publisher = {Wiley},

month = {feb},

url = {https://doi.org/10.1002%2Ftcr.202100009},

number = {9},

pages = {2148--2163},

doi = {10.1002/tcr.202100009}

}

MLA

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MLA Copy

Budnikova, Yulia H.. “Electrochemical Insight into Mechanisms and Metallocyclic Intermediates of C−H Functionalization.” Chemical Record, vol. 21, no. 9, Feb. 2021, pp. 2148-2163. https://doi.org/10.1002%2Ftcr.202100009.

Found error?

Publisher

Wiley

Journal

Chemical Record

Quartile SCImago

Quartile WOS

Impact factor

6.6

ISSN

15278999 (Print)
15280691 (Electronic)

Labs

Laboratory of Electrochemical Synthesis

Profiles

Budnikova, Yulia H