Anomalous High‐Temperature Superconductivity in YH 6

Pressure‐stabilized hydrides are a new rapidly growing class of high‐temperature superconductors, which is believed to be described within the conventional phonon‐mediated mechanism of coupling. Here, the synthesis of one of the best‐known high‐T_C superconductors—yttrium hexahydride ‐YH₆ is reported, which displays a superconducting transition at ≈224 K at 166 GPa. The extrapolated upper critical magnetic field B_c2(0) of YH₆ is surprisingly high: 116–158 T, which is 2–2.5 times larger than the calculated value. A pronounced shift of T_C in yttrium deuteride YD₆ with the isotope coefficient 0.4 supports the phonon‐assisted superconductivity. Current–voltage measurements show that the critical current I_C and its density J_C may exceed 1.75 A and 3500 A mm⁻² at 4 K, respectively, which is higher than that of the commercial superconductors, such as NbTi and YBCO. The results of superconducting density functional theory (SCDFT) and anharmonic calculations, together with anomalously high critical magnetic field, suggest notable departures of the superconducting properties from the conventional Migdal–Eliashberg and Bardeen–Cooper–Schrieffer theories, and presence of an additional mechanism of superconductivity.