Asymmetric Catalytic Reactions Using P*-Mono-, P*,N- and P*,P*-Bidentate Diamidophosphites with BINOL Backbones and 1,3,2-Diazaphospholidine Moieties: Differences in the Enantioselectivity
Publication type: Journal Article
Publication date: 2010-09-15
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
Abstract
A new series of P*‐chiral diamidophosphites with 1,3,2‐diazaphospholidine rings, based on (Sa)‐ or (Ra)‐BINOL and their easily accessible derivatives, has been synthesized for the first time and tested in asymmetric transition metal catalysis. Up to 99% ee was achieved in the rhodium‐catalyzed asymmetric hydrogenation of functionalized olefins and in the palladium‐catalyzed allylic substitution. The influence of the nature of the donor atoms and denticity on the asymmetric induction is discussed. In addition, the first example of a successful platinum‐catalyzed asymmetric allylic amination (up to 86% ee) with participation of organophosphorus ligands is considered.
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Gavrilov K. N. et al. Asymmetric Catalytic Reactions Using P*-Mono-, P*,N- and P*,P*-Bidentate Diamidophosphites with BINOL Backbones and 1,3,2-Diazaphospholidine Moieties: Differences in the Enantioselectivity // Advanced Synthesis and Catalysis. 2010. Vol. 352. No. 14-15. pp. 2599-2610.
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Gavrilov K. N., Zheglov S. V., Rastorguev E. A., Groshkin N. N., Maksimova M. G., Benetsky E. B., Davankov V. A., Reetz M. T. Asymmetric Catalytic Reactions Using P*-Mono-, P*,N- and P*,P*-Bidentate Diamidophosphites with BINOL Backbones and 1,3,2-Diazaphospholidine Moieties: Differences in the Enantioselectivity // Advanced Synthesis and Catalysis. 2010. Vol. 352. No. 14-15. pp. 2599-2610.
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TY - JOUR
DO - 10.1002/adsc.201000325
UR - https://onlinelibrary.wiley.com/doi/10.1002/adsc.201000325
TI - Asymmetric Catalytic Reactions Using P*-Mono-, P*,N- and P*,P*-Bidentate Diamidophosphites with BINOL Backbones and 1,3,2-Diazaphospholidine Moieties: Differences in the Enantioselectivity
T2 - Advanced Synthesis and Catalysis
AU - Gavrilov, Konstantin N
AU - Zheglov, Sergey V
AU - Rastorguev, Eugenie A
AU - Groshkin, Nikolay N
AU - Maksimova, Marina G
AU - Benetsky, Eduard B
AU - Davankov, Vadim A
AU - Reetz, Manfred T.
PY - 2010
DA - 2010/09/15
PB - Wiley
SP - 2599-2610
IS - 14-15
VL - 352
SN - 1615-4150
SN - 1615-4169
ER -
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@article{2010_Gavrilov,
author = {Konstantin N Gavrilov and Sergey V Zheglov and Eugenie A Rastorguev and Nikolay N Groshkin and Marina G Maksimova and Eduard B Benetsky and Vadim A Davankov and Manfred T. Reetz},
title = {Asymmetric Catalytic Reactions Using P*-Mono-, P*,N- and P*,P*-Bidentate Diamidophosphites with BINOL Backbones and 1,3,2-Diazaphospholidine Moieties: Differences in the Enantioselectivity},
journal = {Advanced Synthesis and Catalysis},
year = {2010},
volume = {352},
publisher = {Wiley},
month = {sep},
url = {https://onlinelibrary.wiley.com/doi/10.1002/adsc.201000325},
number = {14-15},
pages = {2599--2610},
doi = {10.1002/adsc.201000325}
}
Cite this
MLA
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Gavrilov, Konstantin N., et al. “Asymmetric Catalytic Reactions Using P*-Mono-, P*,N- and P*,P*-Bidentate Diamidophosphites with BINOL Backbones and 1,3,2-Diazaphospholidine Moieties: Differences in the Enantioselectivity.” Advanced Synthesis and Catalysis, vol. 352, no. 14-15, Sep. 2010, pp. 2599-2610. https://onlinelibrary.wiley.com/doi/10.1002/adsc.201000325.