Oxidative Annulation of Anilides with Internal Alkynes Using an (Electron‐Deficient η5‐Cyclopentadienyl)Rhodium(III) Catalyst Under Ambient Conditions
Publication type: Journal Article
Publication date: 2014-01-31
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract
A dinuclear (electron‐deficient η5‐cyclopentadienyl)rhodium(III) complex was synthesized on a preparative scale via the rhodium‐catalyzed cross [2+2+1] cyclotrimerization of silylacetylenes and two alkynyl esters, leading to substituted silylfulvenes, followed by reductive complexation with rhodium(III) chloride in ethanol. The thus obtained dinuclear (electron‐deficient η5‐cyclopentadienyl)rhodium(III) complex is a highly active precatalyst for the oxidative annulation of anilides with internal alkynes under ambient conditions (at room temperature under air). A preference for annulation across electron‐rich substrates over electron‐deficient substrates was observed using this electron‐deficient rhodium(III) complex.
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137
Total citations:
137
Citations from 2025:
2
(1.46%)
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GOST
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Hoshino Y. et al. Oxidative Annulation of Anilides with Internal Alkynes Using an (Electron‐Deficient η5‐Cyclopentadienyl)Rhodium(III) Catalyst Under Ambient Conditions // Advanced Synthesis and Catalysis. 2014. Vol. 356. No. 7. pp. 1577-1585.
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Hoshino Y., Shibata Yu., Tanaka K. Oxidative Annulation of Anilides with Internal Alkynes Using an (Electron‐Deficient η5‐Cyclopentadienyl)Rhodium(III) Catalyst Under Ambient Conditions // Advanced Synthesis and Catalysis. 2014. Vol. 356. No. 7. pp. 1577-1585.
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RIS
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TY - JOUR
DO - 10.1002/adsc.201300884
UR - https://onlinelibrary.wiley.com/doi/10.1002/adsc.201300884
TI - Oxidative Annulation of Anilides with Internal Alkynes Using an (Electron‐Deficient η5‐Cyclopentadienyl)Rhodium(III) Catalyst Under Ambient Conditions
T2 - Advanced Synthesis and Catalysis
AU - Hoshino, Yuki
AU - Shibata, Yu
AU - Tanaka, Ken-ichi
PY - 2014
DA - 2014/01/31
PB - Wiley
SP - 1577-1585
IS - 7
VL - 356
SN - 1615-4150
SN - 1615-4169
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Hoshino,
author = {Yuki Hoshino and Yu Shibata and Ken-ichi Tanaka},
title = {Oxidative Annulation of Anilides with Internal Alkynes Using an (Electron‐Deficient η5‐Cyclopentadienyl)Rhodium(III) Catalyst Under Ambient Conditions},
journal = {Advanced Synthesis and Catalysis},
year = {2014},
volume = {356},
publisher = {Wiley},
month = {jan},
url = {https://onlinelibrary.wiley.com/doi/10.1002/adsc.201300884},
number = {7},
pages = {1577--1585},
doi = {10.1002/adsc.201300884}
}
Cite this
MLA
Copy
Hoshino, Yuki, et al. “Oxidative Annulation of Anilides with Internal Alkynes Using an (Electron‐Deficient η5‐Cyclopentadienyl)Rhodium(III) Catalyst Under Ambient Conditions.” Advanced Synthesis and Catalysis, vol. 356, no. 7, Jan. 2014, pp. 1577-1585. https://onlinelibrary.wiley.com/doi/10.1002/adsc.201300884.