CH Activation of Isobutylene Using Frustrated Lewis Pairs: Aluminum and Boron σ-Allyl Complexes
Publication type: Journal Article
Publication date: 2012-03-23
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
22447372
General Chemistry
Catalysis
Abstract
Activation frustration: The frustrated Lewis pairs derived from the Lewis base, tBu3P, and the Lewis acids, Al(C6F5)3 and B(C6F5)3, react with isobutylene to give complexes 1 and 2, respectively. Compound 1 reacts with ethylene to give the insertion product, CH2C(CH3)(CH2)3Al(C6F5)2, and [tBu3PH][Al(C6F5)4] as the major products, and the zwitterion tBu3PCH2CH2Al(C6F5)3 and residual Al(C6F5)3 as the minor products.
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Total citations:
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Citations from 2025:
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GOST
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Ménard G., Stephan D. W. CH Activation of Isobutylene Using Frustrated Lewis Pairs: Aluminum and Boron σ-Allyl Complexes // Angewandte Chemie - International Edition. 2012. Vol. 51. No. 18. pp. 4409-4412.
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Ménard G., Stephan D. W. CH Activation of Isobutylene Using Frustrated Lewis Pairs: Aluminum and Boron σ-Allyl Complexes // Angewandte Chemie - International Edition. 2012. Vol. 51. No. 18. pp. 4409-4412.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201200328
UR - https://doi.org/10.1002/anie.201200328
TI - CH Activation of Isobutylene Using Frustrated Lewis Pairs: Aluminum and Boron σ-Allyl Complexes
T2 - Angewandte Chemie - International Edition
AU - Ménard, Gabriel
AU - Stephan, Douglas W.
PY - 2012
DA - 2012/03/23
PB - Wiley
SP - 4409-4412
IS - 18
VL - 51
PMID - 22447372
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2012_Ménard,
author = {Gabriel Ménard and Douglas W. Stephan},
title = {CH Activation of Isobutylene Using Frustrated Lewis Pairs: Aluminum and Boron σ-Allyl Complexes},
journal = {Angewandte Chemie - International Edition},
year = {2012},
volume = {51},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/anie.201200328},
number = {18},
pages = {4409--4412},
doi = {10.1002/anie.201200328}
}
Cite this
MLA
Copy
Ménard, Gabriel, and Douglas W. Stephan. “CH Activation of Isobutylene Using Frustrated Lewis Pairs: Aluminum and Boron σ-Allyl Complexes.” Angewandte Chemie - International Edition, vol. 51, no. 18, Mar. 2012, pp. 4409-4412. https://doi.org/10.1002/anie.201200328.