Enantioselective Sulfonation of Enones with Sulfonyl Imines by Cooperative N-Heterocyclic-Carbene/Thiourea/Tertiary-Amine Multicatalysis
Publication type: Journal Article
Publication date: 2013-10-02
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
24115649
General Chemistry
Catalysis
Abstract
Many hands make light work: In an organocatalytic asymmetric sulfonation of enones, the activation of a sulfonyl imine by an N-heterocyclic carbene (NHC) catalyst led to the release of a sulfinic anion, which underwent nucleophilic addition to the enone. The enantioselectivity of the process was controlled by a chiral thiourea/amine co-catalyst through anion recognition and hydrogen-bonding interactions. Tol=p-tolyl.
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117
Total citations:
117
Citations from 2025:
9
(7.69%)
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GOST
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Jin Z. et al. Enantioselective Sulfonation of Enones with Sulfonyl Imines by Cooperative N-Heterocyclic-Carbene/Thiourea/Tertiary-Amine Multicatalysis // Angewandte Chemie - International Edition. 2013. Vol. 52. No. 47. pp. 12354-12358.
GOST all authors (up to 50)
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Jin Z., Xu J., Yang S., Song B., Chi Y. R. Enantioselective Sulfonation of Enones with Sulfonyl Imines by Cooperative N-Heterocyclic-Carbene/Thiourea/Tertiary-Amine Multicatalysis // Angewandte Chemie - International Edition. 2013. Vol. 52. No. 47. pp. 12354-12358.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201305023
UR - https://doi.org/10.1002/anie.201305023
TI - Enantioselective Sulfonation of Enones with Sulfonyl Imines by Cooperative N-Heterocyclic-Carbene/Thiourea/Tertiary-Amine Multicatalysis
T2 - Angewandte Chemie - International Edition
AU - Jin, Zhichao
AU - Xu, Jianfeng
AU - Yang, Song
AU - Song, Baoan
AU - Chi, Yonggui Robin
PY - 2013
DA - 2013/10/02
PB - Wiley
SP - 12354-12358
IS - 47
VL - 52
PMID - 24115649
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Jin,
author = {Zhichao Jin and Jianfeng Xu and Song Yang and Baoan Song and Yonggui Robin Chi},
title = {Enantioselective Sulfonation of Enones with Sulfonyl Imines by Cooperative N-Heterocyclic-Carbene/Thiourea/Tertiary-Amine Multicatalysis},
journal = {Angewandte Chemie - International Edition},
year = {2013},
volume = {52},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/anie.201305023},
number = {47},
pages = {12354--12358},
doi = {10.1002/anie.201305023}
}
Cite this
MLA
Copy
Jin, Zhichao, et al. “Enantioselective Sulfonation of Enones with Sulfonyl Imines by Cooperative N-Heterocyclic-Carbene/Thiourea/Tertiary-Amine Multicatalysis.” Angewandte Chemie - International Edition, vol. 52, no. 47, Oct. 2013, pp. 12354-12358. https://doi.org/10.1002/anie.201305023.