A New Golden Age for Donor-Acceptor Cyclopropanes
Publication type: Journal Article
Publication date: 2014-04-25
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
24771660
General Chemistry
Catalysis
Abstract
The effective use of ring strain has been applied to considerable advantage for the construction of complex systems. The focus here is directed towards cyclopropanes as building blocks for organic synthesis. Although thermodynamics should take the side of synthetic chemists, only a specific substitution pattern at the cyclopropane ring allows for particularly mild, efficient, and selective transformations. The required decrease in the activation barrier is achieved by the combined effects of vicinal electron-donating and electron-accepting moieties. This Review highlights the appropriate tools for successfully employing donor-acceptor cyclopropanes in ring-opening reactions, cycloadditions, and rearrangements.
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1.1k
Total citations:
1119
Citations from 2024:
209
(18%)
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GOST
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Schneider T. F., Kaschel J., Werz D. B. A New Golden Age for Donor-Acceptor Cyclopropanes // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 22. pp. 5504-5523.
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Schneider T. F., Kaschel J., Werz D. B. A New Golden Age for Donor-Acceptor Cyclopropanes // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 22. pp. 5504-5523.
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RIS
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TY - JOUR
DO - 10.1002/anie.201309886
UR - https://doi.org/10.1002/anie.201309886
TI - A New Golden Age for Donor-Acceptor Cyclopropanes
T2 - Angewandte Chemie - International Edition
AU - Schneider, Tobias F
AU - Kaschel, Johannes
AU - Werz, Daniel B.
PY - 2014
DA - 2014/04/25
PB - Wiley
SP - 5504-5523
IS - 22
VL - 53
PMID - 24771660
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Schneider,
author = {Tobias F Schneider and Johannes Kaschel and Daniel B. Werz},
title = {A New Golden Age for Donor-Acceptor Cyclopropanes},
journal = {Angewandte Chemie - International Edition},
year = {2014},
volume = {53},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/anie.201309886},
number = {22},
pages = {5504--5523},
doi = {10.1002/anie.201309886}
}
Cite this
MLA
Copy
Schneider, Tobias F., et al. “A New Golden Age for Donor-Acceptor Cyclopropanes.” Angewandte Chemie - International Edition, vol. 53, no. 22, Apr. 2014, pp. 5504-5523. https://doi.org/10.1002/anie.201309886.