Angewandte Chemie - International Edition, volume 53, issue 22, pages 5504-5523
A New Golden Age for Donor-Acceptor Cyclopropanes
Publication type: Journal Article
Publication date: 2014-04-25
Q1
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
The effective use of ring strain has been applied to considerable advantage for the construction of complex systems. The focus here is directed towards cyclopropanes as building blocks for organic synthesis. Although thermodynamics should take the side of synthetic chemists, only a specific substitution pattern at the cyclopropane ring allows for particularly mild, efficient, and selective transformations. The required decrease in the activation barrier is achieved by the combined effects of vicinal electron-donating and electron-accepting moieties. This Review highlights the appropriate tools for successfully employing donor-acceptor cyclopropanes in ring-opening reactions, cycloadditions, and rearrangements.
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Schneider T. F., Kaschel J., Werz D. B. A New Golden Age for Donor-Acceptor Cyclopropanes // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 22. pp. 5504-5523.
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Schneider T. F., Kaschel J., Werz D. B. A New Golden Age for Donor-Acceptor Cyclopropanes // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 22. pp. 5504-5523.
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TY - JOUR
DO - 10.1002/anie.201309886
UR - https://doi.org/10.1002/anie.201309886
TI - A New Golden Age for Donor-Acceptor Cyclopropanes
T2 - Angewandte Chemie - International Edition
AU - Schneider, Tobias F
AU - Kaschel, Johannes
AU - Werz, Daniel B.
PY - 2014
DA - 2014/04/25
PB - Wiley
SP - 5504-5523
IS - 22
VL - 53
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex (up to 50 authors)
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@article{2014_Schneider,
author = {Tobias F Schneider and Johannes Kaschel and Daniel B. Werz},
title = {A New Golden Age for Donor-Acceptor Cyclopropanes},
journal = {Angewandte Chemie - International Edition},
year = {2014},
volume = {53},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/anie.201309886},
number = {22},
pages = {5504--5523},
doi = {10.1002/anie.201309886}
}
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Schneider, Tobias F., et al. “A New Golden Age for Donor-Acceptor Cyclopropanes.” Angewandte Chemie - International Edition, vol. 53, no. 22, Apr. 2014, pp. 5504-5523. https://doi.org/10.1002/anie.201309886.